NTA JEE Main 2025 April 02 Shift 2

NTA JEE Main 2025 April 02 Shift 2 - Question 1

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If the image of the point $$P(1, 0, 3)$$ in the line joining the points $$A(4, 7, 1)$$ and $$B(3, 5, 3)$$ is $$Q(\alpha, \beta, \gamma)$$, then $$\alpha + \beta + \gamma$$ is equal to

A

$$\frac{47}{3}$$

B

$$\frac{46}{3}$$

C

$$18$$

D

$$13$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 2

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Let $$f : [1, \infty) \to [2, \infty)$$ be a differentiable function. If $$10\int_{1}^{x} f(t)\,dt = 5xf(x) - x^5 - 9$$ for all $$x \geq 1$$, then the value of $$f(3)$$ is :

A

$$18$$

B

$$32$$

C

$$22$$

D

$$26$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 3

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The number of terms of an A.P. is even; the sum of all the odd terms is 24, the sum of all the even terms is 30 and the last term exceeds the first by $$\frac{21}{2}$$. Then the number of terms which are integers in the A.P. is :

A

$$4$$

B

$$10$$

C

$$6$$

D

$$8$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 4

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Let $$A = \{1, 2, 3, \ldots, 100\}$$ and R be a relation on A such that $$R = \{(a, b) : a = 2b + 1\}$$. Let $$(a_1, a_2), (a_2, a_3), (a_3, a_4), \ldots, (a_k, a_{k+1})$$ be a sequence of k elements of R such that the second entry of an ordered pair is equal to the first entry of the next ordered pair. Then the largest integer k, for which such a sequence exists, is equal to :

A

$$6$$

B

$$7$$

C

$$5$$

D

$$8$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 5

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If the length of the minor axis of an ellipse is equal to one fourth of the distance between the foci, then the eccentricity of the ellipse is :

A

$$\frac{4}{\sqrt{17}}$$

B

$$\frac{\sqrt{3}}{16}$$

C

$$\frac{3}{\sqrt{19}}$$

D

$$\frac{\sqrt{5}}{7}$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 6

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The line $$L_1$$ is parallel to the vector $$\vec{a} = -3\hat{i} + 2\hat{j} + 4\hat{k}$$ and passes through the point $$(7, 6, 2)$$ and the line $$L_2$$ is parallel to the vector $$\vec{b} = 2\hat{i} + \hat{j} + 3\hat{k}$$ and passes through the point $$(5, 3, 4)$$. The shortest distance between the lines $$L_1$$ and $$L_2$$ is :

A

$$\frac{23}{\sqrt{38}}$$

B

$$\frac{21}{\sqrt{57}}$$

C

$$\frac{23}{\sqrt{57}}$$

D

$$\frac{21}{\sqrt{38}}$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 7

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Let $$(a, b)$$ be the point of intersection of the curve $$x^2 = 2y$$ and the straight line $$y - 2x - 6 = 0$$ in the second quadrant. Then the integral $$I = \int_{a}^{b} \frac{9x^2}{1 + 5^x}\,dx$$ is equal to :

A

$$24$$

B

$$27$$

C

$$18$$

D

$$21$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 8

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If the system of equations
$$2x + \lambda y + 3z = 5$$
$$3x + 2y - z = 7$$
$$4x + 5y + \mu z = 9$$
has infinitely many solutions, then $$(\lambda^2 + \mu^2)$$ is equal to :

A

$$22$$

B

$$18$$

C

$$26$$

D

$$30$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 9

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If $$\theta \in \left[-\frac{7\pi}{6}, \frac{4\pi}{3}\right]$$, then the number of solutions of $$\sqrt{3}\csc^2\theta - 2(\sqrt{3} - 1)\csc\theta - 4 = 0$$, is equal to

A

$$6$$

B

$$8$$

C

$$10$$

D

$$7$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 10

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Given three identical bags each containing 10 balls, whose colours are as follows :

Bag I : 3 Red, 2 Blue, 5 Green
Bag II : 4 Red, 3 Blue, 3 Green
Bag III : 5 Red, 1 Blue, 4 Green

A person chooses a bag at random and takes out a ball. If the ball is Red, the probability that it is from bag I is p and if the ball is Green, the probability that it is from bag III is q, then the value of $$\left(\frac{1}{p} + \frac{1}{q}\right)$$ is :

A

$$6$$

B

$$9$$

C

$$7$$

D

$$8$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 11

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If the mean and the variance of 6, 4, a, 8, b, 12, 10, 13 are 9 and 9.25 respectively, then $$a + b + ab$$ is equal to :

A

$$105$$

B

$$103$$

C

$$100$$

D

$$106$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 12

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If the domain of the function $$f(x) = \frac{1}{\sqrt{10 + 3x - x^2}} + \frac{1}{\sqrt{x + |x|}}$$ is $$(a, b)$$, then $$(1 + a)^2 + b^2$$ is equal to :

A

$$26$$

B

$$29$$

C

$$25$$

D

$$30$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 13

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$$4\int_{0}^{1} \frac{1}{\sqrt{3 + x^2} + \sqrt{1 + x^2}} \, dx - 3\log_e(\sqrt{3})$$ is equal to :

A

$$2 + \sqrt{2} + \log_e(1 + \sqrt{2})$$

B

$$2 - \sqrt{2} - \log_e(1 + \sqrt{2})$$

C

$$2 + \sqrt{2} - \log_e(1 + \sqrt{2})$$

D

$$2 - \sqrt{2} + \log_e(1 + \sqrt{2})$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 14

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If $$\lim_{x \to 0} \frac{\cos(2x) + a\cos(4x) - b}{x^4}$$ is finite, then $$(a + b)$$ is equal to :

A

$$\frac{1}{2}$$

B

$$0$$

C

$$\frac{3}{4}$$

D

$$-1$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 15

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If $$\sum_{r=0}^{10} \left(\frac{10^{r+1} - 1}{10^r}\right) \cdot \,^{11}C_{r+1} = \frac{\alpha^{11} - 11^{11}}{10^{10}}$$, then $$\alpha$$ is equal to :

A

$$15$$

B

$$11$$

C

$$24$$

D

$$20$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 16

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The number of ways, in which the letters A, B, C, D, E can be placed in the 8 boxes of the figure below so that no row remains empty and at most one letter can be placed in a box, is :

A

$$5880$$

B

$$960$$

C

$$840$$

D

$$5760$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 17

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Let the point P of the focal chord PQ of the parabola $$y^2 = 16x$$ be $$(1, -4)$$. If the focus of the parabola divides the chord PQ in the ratio $$m : n$$, $$\gcd(m, n) = 1$$, then $$m^2 + n^2$$ is equal to :

A

$$17$$

B

$$10$$

C

$$37$$

D

$$26$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 18

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Let $$\vec{a} = 2\hat{i} - 3\hat{j} + \hat{k}$$, $$\vec{b} = 3\hat{i} + 2\hat{j} + 5\hat{k}$$ and a vector $$\vec{c}$$ be such that $$(\vec{a} - \vec{c}) \times \vec{b} = -18\hat{i} - 3\hat{j} + 12\hat{k}$$ and $$\vec{a} \cdot \vec{c} = 3$$. If $$\vec{b} \times \vec{c} = \vec{d}$$, then $$|\vec{a} \cdot \vec{d}|$$ is equal to :

A

$$18$$

B

$$12$$

C

$$9$$

D

$$15$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 19

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Let the area of the triangle formed by a straight line $$L : x + by + c = 0$$ with co-ordinate axes be 48 square units. If the perpendicular drawn from the origin to the line L makes an angle of 45° with the positive x-axis, then the value of $$b^2 + c^2$$ is :

A

$$90$$

B

$$93$$

C

$$97$$

D

$$83$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 20

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Let A be a $$3 \times 3$$ real matrix such that $$A^2(A - 2I) - 4(A - I) = O$$, where I and O are the identity and null matrices, respectively. If $$A^5 = \alpha A^2 + \beta A + \gamma I$$, where $$\alpha, \beta$$ and $$\gamma$$ are real constants, then $$\alpha + \beta + \gamma$$ is equal to :

A

$$12$$

B

$$20$$

C

$$76$$

D

$$4$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 21

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Let $$y = y(x)$$ be the solution of the differential equation $$\frac{dy}{dx} + 2y\sec^2 x = 2\sec^2 x + 3\tan x \cdot \sec^2 x$$ such that $$y(0) = \frac{5}{4}$$. Then $$12\left(y\left(\frac{\pi}{4}\right) - e^{-2}\right)$$ is equal to __________.

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NTA JEE Main 2025 April 02 Shift 2 - Question 22

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If the sum of the first 10 terms of the series $$\frac{4 \cdot 1}{1 + 4 \cdot 1^4} + \frac{4 \cdot 2}{1 + 4 \cdot 2^4} + \frac{4 \cdot 3}{1 + 4 \cdot 3^4} + \ldots$$ is $$\frac{m}{n}$$, where $$\gcd(m, n) = 1$$, then $$m + n$$ is equal to __________.

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NTA JEE Main 2025 April 02 Shift 2 - Question 23

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If $$y = \cos\left(\frac{\pi}{3} + \cos^{-1}\frac{x}{2}\right)$$, then $$(x - y)^2 + 3y^2$$ is equal to __________.

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NTA JEE Main 2025 April 02 Shift 2 - Question 24

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Let $$A(4, -2)$$, $$B(1, 1)$$ and $$C(9, -3)$$ be the vertices of a triangle ABC. Then the maximum area of the parallelogram AFDE, formed with vertices D, E and F on the sides BC, CA and AB of the triangle ABC respectively, is __________.

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NTA JEE Main 2025 April 02 Shift 2 - Question 25

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If the set of all $$a \in \mathbb{R} - \{1\}$$, for which the roots of the equation $$(1 - a)x^2 + 2(a - 3)x + 9 = 0$$ are positive is $$(-\infty, -\alpha] \cup [\beta, \gamma)$$, then $$2\alpha + \beta + \gamma$$ is equal to __________.

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NTA JEE Main 2025 April 02 Shift 2 - Question 26

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Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).

Assertion (A) : Net dipole moment of a polar linear isotropic dielectric substance is not zero even in the absence of an external electric field.

Reason (R) : In absence of an external electric field, the different permanent dipoles of a polar dielectric substance are oriented in random directions.

In the light of the above statements, choose the most appropriate answer from the options given below :

A

(A) is correct but (R) is not correct

B

Both (A) and (R) are correct but (R) is not the correct explanation of (A)

C

Both (A) and (R) are correct and (R) is the correct explanation of (A)

D

(A) is not correct but (R) is correct

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NTA JEE Main 2025 April 02 Shift 2 - Question 27

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In a moving coil galvanometer, two moving coils $$M_1$$ and $$M_2$$ have the following particulars :
$$R_1 = 5\,\Omega$$, $$N_1 = 15$$, $$A_1 = 3.6 \times 10^{-3}\,\text{m}^2$$, $$B_1 = 0.25\,\text{T}$$
$$R_2 = 7\,\Omega$$, $$N_2 = 21$$, $$A_2 = 1.8 \times 10^{-3}\,\text{m}^2$$, $$B_2 = 0.50\,\text{T}$$
Assuming that torsional constant of the springs are same for both coils, what will be the ratio of voltage sensitivity of $$M_1$$ and $$M_2$$ ?

A

$$1 : 1$$

B

$$1 : 4$$

C

$$1 : 3$$

D

$$1 : 2$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 28

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The moment of inertia of a circular ring of mass M and diameter r about a tangential axis lying in the plane of the ring is :

A

$$\frac{1}{2}Mr^2$$

B

$$\frac{3}{8}Mr^2$$

C

$$\frac{3}{2}Mr^2$$

D

$$2Mr^2$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 29

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Two water drops each of radius 'r' coalesce to form a bigger drop. If 'T' is the surface tension, the surface energy released in this process is :

A

$$4\pi r^2 T\left[2 - 2^{\frac{2}{3}}\right]$$

B

$$4\pi r^2 T\left[2 - 2^{\frac{1}{3}}\right]$$

C

$$4\pi r^2 T\left[1 + \sqrt{2}\right]$$

D

$$4\pi r^2 T\left[\sqrt{2} - 1\right]$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 30

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An electron with mass 'm' with an initial velocity $$(t = 0)$$ $$\vec{v} = v_0\hat{i}$$ $$(v_0 \gt 0)$$ enters a magnetic field $$\vec{B} = B_0\hat{j}$$. If the initial de-Broglie wavelength at $$t = 0$$ is $$\lambda_0$$ then its value after time 't' would be :

A

$$\frac{\lambda_0}{\sqrt{1 - \frac{e^2 B_0^2 t^2}{m^2}}}$$

B

$$\frac{\lambda_0}{\sqrt{1 + \frac{e^2 B_0^2 t^2}{m^2}}}$$

C

$$\lambda_0\sqrt{1 + \frac{e^2 B_0^2 t^2}{m^2}}$$

D

$$\lambda_0$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 31

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A sinusoidal wave of wavelength 7.5 cm travels a distance of 1.2 cm along the x-direction in 0.3 sec. The crest P is at $$x = 0$$ at $$t = 0$$ sec and maximum displacement of the wave is 2 cm. Which equation correctly represents this wave ?

A

$$y = 2\cos(0.83x - 3.35t)$$ cm

B

$$y = 2\sin(0.83x - 3.5t)$$ cm

C

$$y = 2\cos(3.35x - 0.83t)$$ cm

D

$$y = 2\cos(0.13x - 0.5t)$$ cm

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NTA JEE Main 2025 April 02 Shift 2 - Question 32

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Given a charge q, current I and permeability of vacuum $$\mu_0$$. Which of the following quantity has the dimension of momentum ?

A

$$qI/\mu_0$$

B

$$q\mu_0 I$$

C

$$q^2\mu_0 I$$

D

$$q\mu_0/I$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 33

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A solenoid having area A and length 'l' is filled with a material having relative permeability 2. The magnetic energy stored in the solenoid is :

A

$$\frac{B^2 Al}{\mu_0}$$

B

$$\frac{B^2 Al}{2\mu_0}$$

C

$$B^2 Al$$

D

$$\frac{B^2 Al}{4\mu_0}$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 34

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Two large plane parallel conducting plates are kept 10 cm apart as shown in figure. The potential difference between them is V. The potential difference between the points A and B (shown in the figure) is :

A

$$\frac{1}{4}V$$

B

$$\frac{2}{5}V$$

C

$$\frac{3}{4}V$$

D

$$1\,V$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 35

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Identify the characteristics of an adiabatic process in a monoatomic gas.
(A) Internal energy is constant.
(B) Work done in the process is equal to the change in internal energy.
(C) The product of temperature and volume is a constant.
(D) The product of pressure and volume is a constant.
(E) The work done to change the temperature from $$T_1$$ to $$T_2$$ is proportional to $$(T_2 - T_1)$$

Choose the correct answer from the options given below :

A

(A), (C), (D) only

B

(A), (C), (E) only

C

(B), (E) only

D

(B), (D) only

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NTA JEE Main 2025 April 02 Shift 2 - Question 36

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Assuming the validity of Bohr's atomic model for hydrogen like ions the radius of $$Li^{2+}$$ ion in its ground state is given by $$\frac{1}{X}a_0$$, where $$X =$$ ________. (Where $$a_0$$ is the first Bohr's radius.)

A

$$2$$

B

$$1$$

C

$$3$$

D

$$9$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 37

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Energy released when two deuterons $$(_{1}H^2)$$ fuse to form a helium nucleus $$(_{2}He^4)$$ is :
(Given : Binding energy per nucleon of $$_{1}H^2 = 1.1$$ MeV and binding energy per nucleon of $$_{2}He^4 = 7.0$$ MeV)

A

$$8.1$$ MeV

B

$$5.9$$ MeV

C

$$23.6$$ MeV

D

$$26.8$$ MeV

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NTA JEE Main 2025 April 02 Shift 2 - Question 38

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In the digital circuit shown in the figure, for the given inputs the P and Q values are :

A

$$P = 1, Q = 1$$

B

$$P = 0, Q = 0$$

C

$$P = 0, Q = 1$$

D

$$P = 1, Q = 0$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 39

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Two identical objects are placed in front of convex mirror and concave mirror having same radii of curvature of 12 cm, at same distance of 18 cm from the respective mirrors. The ratio of the sizes of images formed by convex mirror and by concave mirror is :

A

$$1/2$$

B

$$2$$

C

$$3$$

D

$$1/3$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 40

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A sportsman runs around a circular track of radius r such that he traverses the path ABAB. The distance travelled and displacement, respectively, are :

A

$$2r, 3\pi r$$

B

$$3\pi r, \pi r$$

C

$$\pi r, 3r$$

D

$$3\pi r, 2r$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 41

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A body of mass 1 kg is suspended with the help of two strings making angles as shown in figure. Magnitude of tensions $$T_1$$ and $$T_2$$, respectively, are (in N) :

A

$$5, 5\sqrt{3}$$

B

$$5\sqrt{3}, 5$$

C

$$5\sqrt{3}, 5\sqrt{3}$$

D

$$5, 5$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 42

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A bi-convex lens has radius of curvature of both the surfaces same as 1/6 cm. If this lens is required to be replaced by another convex lens having different radii of curvatures on both sides $$(R_1 \neq R_2)$$, without any change in lens power then possible combination of $$R_1$$ and $$R_2$$ is :

A

$$\frac{1}{3}$$ cm and $$\frac{1}{3}$$ cm

B

$$\frac{1}{5}$$ cm and $$\frac{1}{7}$$ cm

C

$$\frac{1}{3}$$ cm and $$\frac{1}{7}$$ cm

D

$$\frac{1}{6}$$ cm and $$\frac{1}{9}$$ cm

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NTA JEE Main 2025 April 02 Shift 2 - Question 43

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If $$\mu_0$$ and $$\varepsilon_0$$ are the permeability and permittivity of free space, respectively, then the dimension of $$\left(\frac{1}{\mu_0 \varepsilon_0}\right)$$ is :

A

$$L /T^{-2}$$

B

$$L^2 /T^{2}$$

C

$$T^2/ L$$

D

$$T^2/L^{-2}$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 44

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Match List-I with List-II.

List-I
(A) Heat capacity of body
(B) Specific heat capacity of body
(C) Latent heat
(D) Thermal conductivity

List-II
(I) J kg$$^{-1}$$
(II) J K$$^{-1}$$
(III) J kg$$^{-1}$$ K$$^{-1}$$
(IV) J m$$^{-1}$$ K$$^{-1}$$ s$$^{-1}$$

Choose the correct answer from the options given below :

A

(A)-(III), (B)-(I), (C)-(II), (D)-(IV)

B

(A)-(IV), (B)-(III), (C)-(II), (D)-(I)

C

(A)-(III), (B)-(IV), (C)-(I), (D)-(II)

D

(A)-(II), (B)-(III), (C)-(I), (D)-(IV)

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NTA JEE Main 2025 April 02 Shift 2 - Question 45

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Consider a circular loop that is uniformly charged and has a radius $$a\sqrt{2}$$. Find the position along the positive z-axis of the cartesian coordinate system where the electric field is maximum if the ring was assumed to be placed in xy-plane at the origin :

A

$$\frac{a}{\sqrt{2}}$$

B

$$\frac{a}{2}$$

C

$$a$$

D

$$0$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 46

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A wheel of radius 0.2 m rotates freely about its center when a string that is wrapped over its rim is pulled by force of 10 N as shown in the figure below. The established torque produces an angular acceleration of 2 rad/s$$^2$$. Moment of inertia of the wheel is _________ kg m$$^2$$.
(Acceleration due to gravity = 10 m/s$$^2$$)

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NTA JEE Main 2025 April 02 Shift 2 - Question 47

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The internal energy of air in a $$4\,\text{m} \times 4\,\text{m} \times 3\,\text{m}$$ sized room at 1 atmospheric pressure will be _________ $$\times 10^6$$ J.
(Consider air as diatomic molecule)

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NTA JEE Main 2025 April 02 Shift 2 - Question 48

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A ray of light suffers minimum deviation when incident on a prism having angle of the prism equal to 60°. The refractive index of the prism material is $$\sqrt{2}$$. The angle of incidence (in degrees) is _________.

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NTA JEE Main 2025 April 02 Shift 2 - Question 49

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The length of a light string is 1.4 m when the tension on it is 5 N. If the tension increases to 7 N, the length of the string is 1.56 m. The original length of the string is _________ m.

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NTA JEE Main 2025 April 02 Shift 2 - Question 50

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A satellite of mass 1000 kg is launched to revolve around the earth in an orbit at a height of 270 km from the earth's surface. Kinetic energy of the satellite in this orbit is _________ $$\times 10^{10}$$ J.
(Mass of earth = $$6 \times 10^{24}$$ kg, Radius of earth = $$6.4 \times 10^6$$ m, Gravitational constant = $$6.67 \times 10^{-11}$$ Nm$$^2$$ kg$$^{-2}$$)

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NTA JEE Main 2025 April 02 Shift 2 - Question 51

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When a concentrated solution of sulphanilic acid and 1-naphthylamine is treated with nitrous acid (273 K) and acidified with acetic acid, the mass (g) of 0.1 mole of product formed is :
(Given molar mass in g mol$$^{-1}$$ H : 1, C : 12, N : 14, O : 16, S : 32)

A

$$343$$

B

$$330$$

C

$$33$$

D

$$66$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 52

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The d-orbital electronic configuration of the complex among $$[Co(en)_3]^{3+}$$, $$[CoF_6]^{3-}$$, $$[Mn(H_2O)_6]^{2+}$$ and $$[Zn(H_2O)_6]^{2+}$$ that has the highest CFSE is :

A

$$t_{2g}^{6}e_g^{0}$$

B

$$t_{2g}^{6}e_g^{4}$$

C

$$t_{2g}^{3}e_g^{2}$$

D

$$t_{2g}^{4}e_g^{2}$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 53

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Given below are two statements :

Statement (I) : Neopentane forms only one monosubstituted derivative.
Statement (II) : Melting point of neopentane is higher than n-pentane.

In the light of the above statements, choose the most appropriate answer from the options given below :

A

Statement I is correct but Statement II is incorrect

B

Both Statement I and Statement II are correct

C

Both Statement I and Statement II are incorrect

D

Statement I is incorrect but Statement II is correct

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NTA JEE Main 2025 April 02 Shift 2 - Question 54

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Which among the following molecules is (a) involved in $$sp^3d$$ hybridization, (b) has different bond lengths and (c) has lone pair of electrons on the central atom ?

A

$$PF_5$$

B

$$XeF_4$$

C

$$SF_4$$

D

$$XeF_2$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 55

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Formation of $$Na_4[Fe(CN)_5NOS]$$, a purple coloured complex formed by addition of sodium nitroprusside in sodium carbonate extract of salt indicates the presence of :

A

Sodium ion

B

Sulphate ion

C

Sulphide ion

D

Sulphite ion

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NTA JEE Main 2025 April 02 Shift 2 - Question 56

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In 3,3-dimethylhex-1-ene-4-yne, there are _____ $$sp^3$$, _____ $$sp^2$$ and _____ $$sp$$ hybridised carbon atoms respectively :

A

4, 2, 2

B

3, 3, 2

C

2, 4, 2

D

2, 2, 4

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NTA JEE Main 2025 April 02 Shift 2 - Question 57

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Which of the following statements are true ?
(A) The subsidiary quantum number $$l$$ describes the shape of the orbital occupied by the electron.
(B) 

is the boundary diagram of the $$2p_x$$ orbital.
(C) The + and - signs in the wave function of the $$2p_x$$ orbital refer to charge.
(D) The wave function of $$2p_x$$ orbital is zero everywhere in the xy plane.

A

(B) and (D) only

B

(A), (B) and (C) only

C

(C) and (D) only

D

(A) and (B) only

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NTA JEE Main 2025 April 02 Shift 2 - Question 58

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The type of hybridization and the magnetic property of $$[MnCl_6]^{3-}$$ are :

A

$$d^2sp^3$$, paramagnetic with four unpaired electrons

B

$$sp^3d^2$$, paramagnetic with four unpaired electrons

C

$$d^2sp^3$$, paramagnetic with two unpaired electrons

D

$$sp^3d^2$$, paramagnetic with two unpaired electrons

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NTA JEE Main 2025 April 02 Shift 2 - Question 59

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Consider the following reactions. From these reactions which reaction will give carboxylic acid as a major product ?
(A) $$R-C \equiv N \xrightarrow[\text{mild condition}]{(i) H^+/H_2O}$$
(B) $$R-MgX \xrightarrow[(ii) H_3O^+]{(i) CO_2}$$
(C) $$R-C \equiv N \xrightarrow[(ii) H_3O^+]{(i) SnCl_2/HCl}$$
(D) $$R-CH_2-OH \xrightarrow{PCC}$$
(E) 

Choose the correct answer from the options given below :

A

A and D only

B

A, B and E only

C

B, C and E only

D

B and E only

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NTA JEE Main 2025 April 02 Shift 2 - Question 60

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Electronic configuration of four elements A, B, C and D are given below :
(A) $$1s^2 2s^2 2p^3$$
(B) $$1s^2 2s^2 2p^4$$
(C) $$1s^2 2s^2 2p^5$$
(D) $$1s^2 2s^2 2p^2$$

Which of the following is the correct order of increasing electronegativity (Pauling's scale) ?

A

$$A \lt D \lt B \lt C$$

B

$$A \lt C \lt B \lt D$$

C

$$A \lt B \lt C \lt D$$

D

$$D \lt A \lt B \lt C$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 61

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Match List-I with List-II.

Choose the correct answer from the options given below :

A

(A)-(II), (B)-(III), (C)-(IV), (D)-(I)

B

(A)-(II), (B)-(IV), (C)-(I), (D)-(III)

C

(A)-(III), (B)-(IV), (C)-(II), (D)-(I)

D

(A)-(III), (B)-(I), (C)-(IV), (D)-(II)

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NTA JEE Main 2025 April 02 Shift 2 - Question 62

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'x' g of NaCl is added to water in a beaker with a lid. The temperature of the system is raised from 1°C to 25°C. Which of the following plots, is best suited for the change in the molarity (M) of the solution with respect to temperature ?
[Consider the solubility of NaCl remains unchanged over the temperature range]

A

B

C

D

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NTA JEE Main 2025 April 02 Shift 2 - Question 63

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Arrange the following in order of magnitude of work done by the system / on the system at constant temperature :
(a) $$|w_{\text{reversible}}|$$ for expansion in infinite stage.
(b) $$|w_{\text{irreversible}}|$$ for expansion in single stage.
(c) $$|w_{\text{reversible}}|$$ for compression in infinite stage.
(d) $$|w_{\text{irreversible}}|$$ for compression in single stage.

Choose the correct answer from the options given below :

A

$$a \gt b \gt c \gt d$$

B

$$d \gt c = a \gt b$$

C

$$c = a \gt d \gt b$$

D

$$a \gt c \gt b \gt d$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 64

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Reactant A converts to product D through the given mechanism (with the net evolution of heat) :
$$A \to B$$   slow ; $$\Delta H = +ve$$
$$B \to C$$   fast ; $$\Delta H = -ve$$
$$C \to D$$   fast ; $$\Delta H = -ve$$

Which of the following represents the above reaction mechanism ?

A

B

C

D

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NTA JEE Main 2025 April 02 Shift 2 - Question 65

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The nature of oxide $$(TeO_2)$$ and hydride $$(TeH_2)$$ formed by Te, respectively are :

A

Oxidising and acidic

B

Reducing and basic

C

Reducing and acidic

D

Oxidising and basic

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NTA JEE Main 2025 April 02 Shift 2 - Question 66

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Match List-I with List-II.

Choose the correct answer from the options given below :

A

(A)-(III), (B)-(II), (C)-(IV), (D)-(I)

B

(A)-(III), (B)-(IV), (C)-(II), (D)-(I)

C

(A)-(IV), (B)-(III), (C)-(I), (D)-(II)

D

(A)-(IV), (B)-(I), (C)-(II), (D)-(III)

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NTA JEE Main 2025 April 02 Shift 2 - Question 67

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Consider the following chemical equilibrium of the gas phase reaction at a constant temperature :
$$A(g) \rightleftharpoons B(g) + C(g)$$

If p being the total pressure, $$K_p$$ is the pressure equilibrium constant and $$\alpha$$ is the degree of dissociation, then which of the following is true at equilibrium ?

A

If p value is extremely high compared to $$K_p$$, $$\alpha \approx 1$$

B

When p increases $$\alpha$$ decreases

C

If $$K_p$$ value is extremely high compared to p, $$\alpha$$ becomes much less than unity

D

When p increases $$\alpha$$ increases

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NTA JEE Main 2025 April 02 Shift 2 - Question 68

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Which of the following graphs correctly represents the variation of thermodynamic properties of Haber's process ?

A

B

C

D

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NTA JEE Main 2025 April 02 Shift 2 - Question 69

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A tetrapeptide "x" on complete hydrolysis produced glycine (Gly), alanine (Ala), valine (Val), leucine (Leu) in equimolar proportion each. The number of tetrapeptides (sequences) possible involving each of these amino acids is

A

$$16$$

B

$$32$$

C

$$8$$

D

$$24$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 70

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In Dumas' method for estimation of nitrogen, 0.5 gram of an organic compound gave 60 mL of nitrogen collected at 300 K temperature and 715 mm Hg pressure. The percentage composition of nitrogen in the compound (Aqueous tension at 300 K = 15 mm Hg) is

A

$$1.257$$

B

$$20.87$$

C

$$18.67$$

D

$$12.57$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 71

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For the reaction $$A \to B$$ the following graph was obtained. The time required (in seconds) for the concentration of A to reduce to 2.5 g L$$^{-1}$$ (if the initial concentration of A was 50 g L$$^{-1}$$) is _________.
(Nearest integer)
Given : $$\log 2 = 0.3010$$

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NTA JEE Main 2025 April 02 Shift 2 - Question 72

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0.2 % (w/v) solution of NaOH is measured to have resistivity 870.0 m$$\Omega$$ m. The molar conductivity of the solution will be _________ $$\times 10^2$$ mS dm$$^2$$ mol$$^{-1}$$.
(Nearest integer)

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NTA JEE Main 2025 April 02 Shift 2 - Question 73

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Consider the above sequence of reactions. 151 g of 2-bromopentane is made to react. Yield of major product P is 80% whereas Q is 100%.

Mass of product Q obtained is _________ g.
(Given molar mass in g mol$$^{-1}$$ H: 1, C: 12, O: 16, Br: 80)

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NTA JEE Main 2025 April 02 Shift 2 - Question 74

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When 1 g each of compounds AB and $$AB_2$$ are dissolved in 15 g of water separately, they increased the boiling point of water by 2.7 K and 1.5 K respectively. The atomic mass of A (in amu) is _________ $$\times 10^{-1}$$.
(Nearest integer)
(Given : Molal boiling point elevation constant is 0.5 K kg mol$$^{-1}$$)

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NTA JEE Main 2025 April 02 Shift 2 - Question 75

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The spin-only magnetic moment value of $$M^{n+}$$ ion formed among Ni, Zn, Mn and Cu that has the least enthalpy of atomisation is _________. (in nearest integer)

Here n is equal to the number of diamagnetic complexes among $$K_2[NiCl_4]$$, $$[Zn(H_2O)_6]Cl_2$$, $$K_3[Mn(CN)_6]$$ and $$[Cu(PPh_3)_3I]$$

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