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Question 35

Identify the characteristics of an adiabatic process in a monoatomic gas.
(A) Internal energy is constant.
(B) Work done in the process is equal to the change in internal energy.
(C) The product of temperature and volume is a constant.
(D) The product of pressure and volume is a constant.
(E) The work done to change the temperature from $$T_1$$ to $$T_2$$ is proportional to $$(T_2 - T_1)$$

Choose the correct answer from the options given below :

For an adiabatic process of an ideal gas, the heat exchanged with the surroundings is zero: $$Q = 0$$.

First law of thermodynamics: $$\Delta U = Q + W$$, where $$W$$ is the work done on the gas.
Because $$Q = 0$$, we have

$$\Delta U = W \quad -(1)$$

For a monoatomic ideal gas, the internal energy is $$U = \dfrac{3}{2}nRT$$. Hence

$$\Delta U = \dfrac{3}{2}nR\,(T_2 - T_1) \quad -(2)$$

Using $$(1)$$ and $$(2)$$, the work done on the gas is

$$W = \dfrac{3}{2}nR\,(T_2 - T_1) \quad -(3)$$

Thus, $$W$$ is directly proportional to $$(T_2 - T_1)$$.

For an adiabatic change of an ideal gas, the pressure-volume relation is $$PV^{\gamma} = \text{constant}$$, where $$\gamma = \dfrac{C_P}{C_V}$$. For a monoatomic gas, $$\gamma = \dfrac{5}{3}$$. Consequently

$$TV^{\gamma - 1} = TV^{2/3} = \text{constant}$$,
which is not simply $$TV = \text{constant}$$, and $$PV$$ is also not constant.

Now examine each statement:

Statement (A): “Internal energy is constant.”
From $$(2)$$, $$\Delta U \neq 0$$ when temperature changes, so (A) is false.

Statement (B): “Work done in the process is equal to the change in internal energy.”
Equation $$(1)$$ shows $$W = \Delta U$$ (with the ‘work on the gas’ sign convention). Hence (B) is true.

Statement (C): “The product of temperature and volume is a constant.”
We have $$TV^{2/3} = \text{constant}$$, not $$TV$$. Therefore (C) is false.

Statement (D): “The product of pressure and volume is a constant.”
For adiabatic change, $$PV^{5/3} = \text{constant}$$, so $$PV$$ is not constant. (D) is false.

Statement (E): “The work done to change the temperature from $$T_1$$ to $$T_2$$ is proportional to $$(T_2 - T_1)$$.”
Equation $$(3)$$ confirms this proportionality. Hence (E) is true.

Therefore, only statements (B) and (E) are correct.

Option C (B, E only) is the correct choice.

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