Join WhatsApp Icon JEE WhatsApp Group
Question 66

Match List-I with List-II.

image

Choose the correct answer from the options given below :

To match the reactions in List-I with their corresponding names in List-II, let us analyze each reaction individually.

For reaction (A),

$$2\text{C}_6\text{H}_5\text{-X}+2\text{Na}\xrightarrow{\text{Dry Ether}}\text{C}_6\text{H}_5\text{-C}_6\text{H}_5+2\text{NaX},$$

two molecules of an aryl halide react with sodium metal in dry ether to produce a biaryl compound (biphenyl). This coupling reaction is known as the Fittig reaction.

Hence,

$$\boxed{(A)\rightarrow(III).}$$

For reaction (B),

$$\text{ArN}_2^+\text{X}^-\xrightarrow{\text{Cu}/\text{HCl}}\text{ArCl}+\text{N}_2+\text{CuX},$$

an aryldiazonium salt is treated with copper powder and hydrochloric acid to form an aryl chloride. The use of copper powder instead of cuprous halide identifies this transformation as the Gatterman reaction.

Hence,

$$\boxed{(B)\rightarrow(IV).}$$

For reaction (C),

$$\text{C}_2\text{H}_5\text{Br}+\text{NaI}\xrightarrow{\text{Dry Acetone}}\text{C}_2\text{H}_5\text{I}+\text{NaBr},$$

an alkyl bromide is converted into an alkyl iodide using sodium iodide in dry acetone. This halogen exchange reaction is known as the Finkelstein reaction.

Hence,

$$\boxed{(C)\rightarrow(II).}$$

For reaction (D),

$$\text{CH}_3\text{C(OH)(CH}_3\text{)CH}_3\xrightarrow{\text{HCl}/\text{ZnCl}_2}\text{CH}_3\text{C(Cl)(CH}_3\text{)CH}_3,$$

a tertiary alcohol is converted into the corresponding alkyl chloride using concentrated hydrochloric acid and anhydrous zinc chloride. This reaction is known as the Lucas reaction.

Hence,

$$\boxed{(D)\rightarrow(I).}$$

Therefore, the correct matching is

$$\boxed{(A)\rightarrow(III),\ (B)\rightarrow(IV),\ (C)\rightarrow(II),\ (D)\rightarrow(I).}$$

Thus, the correct answer is

$$\boxed{\text{Option (2).}}$$

Get AI Help

Video Solution

video

Create a FREE account and get:

  • Free JEE Mains Previous Papers PDF
  • Take JEE Mains paper tests

JEE Quant Questions | JEE Quantitative Ability

JEE DILR Questions | LRDI Questions For JEE

JEE Verbal Ability Questions | VARC Questions For JEE

Free JEE Topicwise Questions

JEE Rotational MotionJEE Units & MeasurementsJEE Atomic StructureJEE GravitationJEE Periodic Table & PeriodicityJEE StatisticsJEE Inverse Trigonometric FunctionsJEE Magnetism & Magnetic MaterialsJEE Sequences & SeriesJEE MatricesJEE Alternating CurrentsJEE Carboxylic AcidsJEE Permutations & CombinationsJEE Work, Energy & PowerJEE Electromagnetic InductionJEE Electronic DevicesJEE d and f-Block ElementsJEE Chemical KineticsJEE Heat TransferJEE Three Dimensional GeometryJEE Magnetic Effects of CurrentJEE Hydrocarbons - AromaticJEE Electromagnetic WavesJEE Aldehydes & KetonesJEE Hydrocarbons - AlkanesJEE Applications of DerivativesJEE EquilibriumJEE Indefinite IntegrationJEE Chemical ThermodynamicsJEE ElectrochemistryJEE ProbabilityJEE BiomoleculesJEE Continuity & DifferentiabilityJEE Kinetic Theory of GasesJEE Vector AlgebraJEE Hydrocarbons - AlkynesJEE Differential EquationsJEE Current & ResistanceJEE Straight LinesJEE WavesJEE Redox ReactionsJEE Hydrocarbons - AlkenesJEE DeterminantsJEE SolutionsJEE Ray OpticsJEE Dual Nature of Matter & RadiationJEE Chemical Bonding & Molecular StructureJEE Complex NumbersJEE Sets, Relations & FunctionsJEE Electric Charges & FieldsJEE Laws of MotionJEE Fluid MechanicsJEE Basic Concepts in ChemistryJEE Trigonometric FunctionsJEE LimitsJEE Laws of ThermodynamicsJEE Kinematics - 2D MotionJEE p-Block Elements (Groups 13-18)JEE Simple Harmonic MotionJEE Electric Potential & CapacitanceJEE Coordination CompoundsJEE JEE 2D GeometryJEE CirclesJEE Definite IntegrationJEE EMF & Circuit AnalysisJEE Surface TensionJEE Atoms & NucleiJEE Laboratory Experiments - XIJEE Number SystemJEE Basic Principles of Organic ChemistryJEE Wave OpticsJEE Quadratic EquationsJEE Alcohols, Phenols & EthersJEE Organic Compounds with HalogensJEE DifferentiationJEE Conic SectionsJEE Nitrogen-Containing CompoundsJEE ElasticityJEE Practical Organic ChemistryJEE Kinematics - 1D MotionJEE Purification & CharacterisationJEE Binomial Theorem
Ask AI