Consider $$g(x)=f(x)e^{-x}$$
Since
$$f$$is twice differentiable,
$$g$$ is continuous on $$[0,\pi]$$ and differentiable on $$(0,\pi).$$
Also,
$$g(0)=f(0)e^0=0$$ and $$g(\pi)=f(\pi)e^{-\pi}=0$$
Hence,
$$g(0)=g(\pi)$$
Therefore,
$$g(x)$$ satisfies Rolle’s theorem on $$[0,\pi].$$
So, statement ($$g(x)=f(x)e^{-x}$$ satisfies Rolle’s theorem on $$[0,\pi]$$) is correct.
Now,
$$g'(x)=e^{-x}(f'(x)-f(x))$$
By Rolle’s theorem, there exists $$c\in(0,\pi)$$ such that $$g'(c)=0$$
Therefore,
$$e^{-c}(f'(c)-f(c))=0$$
Since
$$e^{-c}\neq0,$$
$$f'(c)=f(c)$$
Hence, statement (There exists at least one $$c\in(0,\pi)$$ such that $$f'(c)=f(c)$$) is correct.
Given,
$$f''(x)-3f'(x)+2f(x)=e^x\cos x$$
At $$x=\frac\pi2,$$
$$e^{\pi/2}\cos\frac\pi2=0$$
Therefore,
$$f''\left(\frac\pi2\right)-3f'\left(\frac\pi2\right)+2f\left(\frac\pi2\right)=0$$
Hence,statement (There exists at least one $$c\in(0,\pi)$$ such that $$f''(c)-3f'(c)+2f(c)=0$$) is correct.
Therefore,all the given statements are correct