Spontaneous change in optical rotation due to equilibrium:
$$\alpha\mathrm{-D-glucose} \rightleftharpoons \mathrm{open chain} \rightleftharpoons \beta\mathrm{-D-glucose}$$Exhibited by reducing sugars with anomeric carbon.
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Biomolecules
Mutarotation
Spontaneous change in optical rotation due to equilibrium:
$$\alpha\mathrm{-D-glucose} \rightleftharpoons \mathrm{open chain} \rightleftharpoons \beta\mathrm{-D-glucose}$$Exhibited by reducing sugars with anomeric carbon.
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