Amphoteric Nature of Aluminum

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$$ 2Al + 2NaOH + 6H_2O \rightarrow 2Na[Al(OH)_4] + 3H_2 $$
$$ Al_2O_3 + 2NaOH \rightarrow 2NaAlO_2 + H_2O $$

Aluminum reacts with NaOH to form sodium tetrahydroxoaluminate. Aluminum oxide dissolves in NaOH to form sodium metaaluminate.

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