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NTA JEE Main 9th April 2019 Shift 1 - Chemistry

For the following questions answer them individually

For a reaction, N$$_2$$(g) + 3H$$_2$$(g) $$\rightarrow$$ 2NH$$_3$$(g), identify di-hydrogen (H$$_2$$) as a limiting reagent in the following reaction mixtures.

The osmotic pressure of a dilute solution of an ionic compound XY in water is four times that of a solution of 0.01 M BaCl$$_2$$ in water. Assuming complete dissociation of the given ionic compounds in water, the concentration of XY (in mol L$$^{-1}$$) in solution is:

Liquid M and liquid N form an ideal solution. The vapour pressures of pure liquids M and N are 450 and 700 mmHg, respectively, at the same temperature. Then correct statements is:
(x$$_M$$ = Mole fraction of 'M' in solution; x$$_N$$ = Mole fraction of 'N' in solution; y$$_M$$ = Mole fraction of 'M' in vapour phase; y$$_N$$ = Mole fraction of 'N' in vapour phase)

Aniline dissolved in dilute HCl is reacted with sodium nitrite at 0°C. This solution was added dropwise to a solution containing an equimolar mixture of aniline and phenol in dilute HCl. The structure of the major product is: