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NTA JEE Main 17th March 2021 Shift 1 - Chemistry

For the following questions answer them individually

The INCORRECT statement(s) about heavy water is (are):
(A) used as a moderator in nuclear reactor
(B) obtained as a by-product in fertilizer industry.
(C) used for the study of reaction mechanism
(D) has a higher dielectric constant than water
Choose the correct answer from the options given below:

Given below are two statements:
Statement-I: Retardation factor ($$R_f$$) can be measured in meter/centimetre.
Statement-II: $$R_f$$ value of a compound remains constant in all solvents.
Choose the most appropriate answer from the options given below:

The point of intersection and sudden increase in the slope, in the diagram given below, respectively, indicates:

Given below are two statements:
Statement I: Potassium permanganate on heating at 573 K forms potassium manganate.
Statement II: Both potassium permanganate and potassium manganate are tetrahedral and paramagnetic in nature.
In the light of the above statements, choose the most appropriate answer from the options given below:

With respect to drug-enzyme interaction, identify the wrong statement:

The pressure exerted by a non-reactive gaseous mixture of 6.4 g of methane and 8.8 g of carbon dioxide in a 10 L vessel at 27°C is ________ kPa. (Round off to the Nearest Integer).
[Assume gases are ideal, R = 8.314 J mol$$^{-1}$$ K$$^{-1}$$, Atomic masses: C: 12.0 u, H: 1.0 u, O: 16.0 u]

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The standard enthalpies of formation of $$Al_2O_3$$ and CaO are $$-1675$$ kJ mol$$^{-1}$$ and $$-635$$ kJ mol$$^{-1}$$ respectively. For the reaction $$3CaO + 2Al \to 3Ca + Al_2O_3$$ the standard reaction enthalpy $$\Delta_r H^0$$ = ________ kJ. (Round off to the Nearest Integer).

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0.01 moles of a weak acid HA ($$K_a = 2.0 \times 10^{-6}$$) is dissolved in 1.0 L of 0.1M HCl solution. The degree of dissociation of HA is ________ $$\times 10^{-5}$$. (Round off to the Nearest Integer). [Neglect volume change on adding HA and assume degree of dissociation << 1]

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The oxygen dissolved in water exerts a partial pressure of 20 kPa in the vapour above water. The molar solubility of oxygen in water is ________ $$\times 10^{-5}$$ mol dm$$^{-3}$$. (Round off to the Nearest Integer).
[Given: Henry's law constant = $$K_H = 8.0 \times 10^4$$ kPa for O$$_2$$. Density of water with dissolved oxygen = 1.0 kg dm$$^{-3}$$]

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