Dehydration to Alkenes

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$$\text{R--CH}_2\text{--CH}_2\text{OH} \xrightarrow{\text{Conc. H}_2\text{SO}_4, \, 170^\circ\text{C}} \text{R--CH=CH}_2 + \text{H}_2\text{O}$$

Rate of dehydration: $$3^\circ > 2^\circ > 1^\circ$$ (Carbocation stability order; Saytzeff alkene is major). (Corresponds to carbocation stability in the $$E1$$ mechanism).



Notation & Key Points:

    Regioselectivity (Saytzeff's / Zaitsev's Rule): The major product is the more substituted, more stable alkene (alkene with more alkyl groups attached to double-bonded carbons).

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