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NTA JEE Main 1st September 2021 Shift 2 - Chemistry

For the following questions answer them individually

Match List - I with List - II.
List-I (Colloid Preparation Method)   List-II (Chemical Reaction)
(a) Hydrolysis   (i) 2AuCl$$_3$$ + 3HCHO + 3H$$_2$$O $$\rightarrow$$ 2Au(sol) + 3HCOOH + 6HCl
(b) Reduction   (ii) As$$_2$$O$$_3$$ + 3H$$_2$$S $$\rightarrow$$ As$$_2$$S$$_3$$(sol) + 3H$$_2$$O
(c) Oxidation   (iii) SO$$_2$$ + 2H$$_2$$S $$\rightarrow$$ 3S(sol) + 2H$$_2$$O
(d) Double Decomposition   (iv) FeCl$$_3$$ + 3H$$_2$$O $$\rightarrow$$ Fe(OH)$$_3$$(sol) + 3HCl
Choose the most appropriate answer from the options given below:

The Crystal Field Stabilization Energy (CFSE) and magnetic moment (spin-only) of an octahedral aqua complex of a metal ion M$$^{Z+}$$ are $$-0.8\Delta_0$$ and 3.87 BM, respectively. Identify M$$^{Z+}$$:

Given below are two statements:
Statement I : The nucleophilic addition of sodium hydrogen sulphite to an aldehyde or a ketone involves proton transfer to form a stable ion.
Statement II : The nucleophilic addition of hydrogen cyanide to an aldehyde or a ketone yields amine as final product.
In the light of the above statements, choose the most appropriate answer from the options given below:

In the following sequence of reactions a compound A, (molecular formula C$$_6$$H$$_{12}$$O$$_2$$) with a straight chain structure gives a C$$_4$$ carboxylic acid. A is:
$$A \xrightarrow[\mathrm{H_3O^+}]{\mathrm{LiAlH_4}} B \xrightarrow{\text{Oxidation}} \text{C}_4\text{-carboxylic acid}$$

A 50 watt bulb emits monochromatic red light of wavelength of 795 nm. The number of photons emitted per second by the bulb is $$x \times 10^{20}$$. The value of x is _________. (Nearest integer)
[Given: h = $$6.63 \times 10^{-34}$$ Js and c = $$3.0 \times 10^8$$ ms$$^{-1}$$]

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An empty LPG cylinder weighs 14.8 kg. When full, it weighs 29.0 kg and shows a pressure of 3.47 atm. In the course of use at ambient temperature, the mass of the cylinder is reduced to 23.0 kg. The final pressure inside the cylinder is _________ atm. (Nearest integer)
(Assume LPG to be an ideal gas)

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If 80 g of copper sulphate CuSO$$_4$$.5H$$_2$$O is dissolved in deionised water to make 5 L of solution. The concentration of the copper sulphate solution is $$x \times 10^{-3}$$ mol $$L^{-1}$$. The value of x is _________.
[Atomic masses Cu : 63.54u, S : 32u, O : 16u, H : 1u]

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If the conductivity of mercury at 0°C is $$1.07 \times 10^6$$ S m$$^{-1}$$ and the resistance of a cell containing mercury is 0.243$$\Omega$$, then the cell constant of the cell is $$x \times 10^4$$ m$$^{-1}$$. The value of x is _________. (Nearest integer)

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