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NTA JEE Main 9th April 2017 Online - Chemistry

For the following questions answer them individually

The increasing order of the boiling points for the following compounds is:
(I) C$$_2$$H$$_5$$OH    (II) C$$_2$$H$$_5$$Cl    (III) C$$_2$$H$$_5$$CH$$_3$$    (IV) C$$_2$$H$$_5$$OCH$$_3$$

At 300 K, the density of a certain gaseous molecule at 2 bar is double to that of dinitrogen (N$$_2$$) at 4 bar. The molar mass of the gaseous molecule is

A gas undergoes change from state A to state B. In this process, the heat absorbed and work done by the gas is 5 J and 8 J, respectively. Now gas is brought back to A by another process during which 3 J of heat is evolved. In this reverse process of B to A.

The following reaction occurs in the Blast Furnace where iron ore is reduced to iron metal:
Fe$$_2$$O$$_3$$(s) + 3CO(g) $$\rightleftharpoons$$ 2Fe(l) + 3CO$$_2$$(g)
Using the Le Chatelier's principle, predict which one of the following will not disturb the equilibrium?

A solution is prepared by mixing 8.5 g of CH$$_2$$Cl$$_2$$ and 11.95 g of CHCl$$_3$$. If vapour pressure of CH$$_2$$Cl$$_2$$ and CHCl$$_3$$ at 298K are 415 and 200 mm Hg respectively, the mole fraction of CHCl$$_3$$ in vapour form is: (Molar mass of Cl = 35.5 g mol$$^{-1}$$)

To find the standard potential of M$$^{3+}$$/M electrode, the following cell is constituted:
Pt | M/M$$^{3+}$$ (0.001 mol L$$^{-1}$$) / Ag$$^+$$ (0.01 mol L$$^{-1}$$) / Ag
The emf of the cell is found to be 0.421 volt at 298 K. The standard potential of half-reaction M$$^{3+}$$ + 3e$$^-$$ $$\rightarrow$$ M at 298 K will be:
(Given: $$E^\ominus_{Ag^+/Ag}$$ at 298 K = 0.80 volt)

The rate of a reaction quadruples when the temperature changes from 300 to 310 K. The activation energy of this reaction is:
(Assume Activation energy and pre-exponential factor are independent of temperature;
ln(2) = 0.693; R = 8.314 J mol$$^{-1}$$ K$$^{-1}$$)

Adsorption of gas on a surface follows Freundlich adsorption isotherm. The plot of log $$\frac{x}{m}$$ versus log(P) gives a straight line with slope equal to 0.5, then:
($$\frac{x}{m}$$ is the mass of the gas adsorbed per gram of adsorbent)

The correct sequence of decreasing number of $$\pi$$-bonds in the structure of $$H_2SO_3$$, $$H_2SO_4$$ and $$H_2S_2O_7$$ is:

[Co$$_2$$(CO)$$_8$$] displays

A compound of molecular formula C$$_8$$H$$_8$$O$$_2$$ reacts with acetophenone to form a single cross-aldol product in the presence of base. The same compound on reaction with concentrated NaOH forms benzyl alcohol as one of the products. The structure of the compound is:

The incorrect statement among the following is