Sign in
Please select an account to continue using cracku.in
↓ →
Join Our JEE Preparation Group
Prep with like-minded aspirants; Get access to free daily tests and study material.
Basicity of the molecule depends on the availability of the lone pair on the Nitrogen atom.
In (II) the lone pair is a part of the aromatic 6$$\pi$$ electron system. Thus the lone pair is extremely unavailable making (II) the least basic compound.
In (I), the lone pair is involved in resonance with the benzene ring, making it less available.
In (III) and (IV), the lone pair is localized and available for protonation. (IV) is more basic due to lower steric hindrance at the lone pair, making it easier to protonate.
Final basicity order: (IV) > (III) > (I) > (II)
Create a FREE account and get:
Predict your JEE Main percentile, rank & performance in seconds
Educational materials for JEE preparation
Ask our AI anything
AI can make mistakes. Please verify important information.
AI can make mistakes. Please verify important information.