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NTA JEE Main 25th June 2022 Shift 2 - Chemistry

For the following questions answer them individually

The minimum energy that must be possessed by photons in order to produce the photoelectric effect with platinum metal is:
[Given: The threshold frequency of platinum is $$1.3 \times 10^{15}$$ s$$^{-1}$$ and $$h = 6.6 \times 10^{-34}$$ Js]

At $$25°$$C and $$1$$ atm pressure, the enthalpy of combustion of benzene $$1$$ and acetylene $$g$$ are $$-3268$$ kJ mol$$^{-1}$$ and $$-1300$$ kJ mol$$^{-1}$$, respectively. The change in enthalpy for the reaction
$$3C_2H_2(g) \to C_6H_6(l)$$, is

Assertion: The amphoteric behaviour of water is explained by Lewis acid base theory
Reason: water acts as acid with $$NH_3$$ and base with $$H_2S$$

Given below are two statements: one is labelled as Assertion and the other is labelled as Reason.
Assertion: A mixture contains benzoic acid and naphthalene. The pure benzoic acid can be separated out by the use of benzene.
Reason: Benzoic acid is soluble in hot water.
In the light of the above statements, choose the most appropriate answer from the options given below.

Given below are two statements: one is labelled as Assertion and the other is labelled as Reason.
Assertion: Polluted water may have a value of BOD of the order of 17ppm.
Reason: BOD is a measure of oxygen required to oxidise both the biodegradable and non-biodegradable organic material in water.
In the light of the above statements, choose the most appropriate answer from the options given below.

Solute A associates in water. When $$0.7$$ g of solute A is dissolved in $$42.0$$ g of water, it depresses the freezing point by $$0.2°$$C. The percentage association of solute A in water, is
[Given: Molar mass of A $$= 93$$ g mol$$^{-1}$$. Molal depression constant of water is $$1.86$$ K kg mol$$^{-1}$$]

Given below are two statements.
Statement I: During electrolytic refining, blister copper deposits precious metals.
Statement II: In the process of obtaining pure copper by electrolysis method, copper blister is used to make the anode.
In the light of the above statements, choose the correct answer from the options given below.