NTA JEE Main 24th January 2023 Shift 1 - Chemistry

For the following questions answer them individually

It is observed that characteristic X-ray spectra of elements show regularity. When frequency to the power 'n' i.e. $$\nu^n$$ of X-rays emitted is plotted against atomic number Z, the following graph is obtained.

The value of 'n' is

Match Column I with Column II
Column I      Column II
A. Soda ash      I. CaSO$$_4$$
B. Chlorophyll      II. CaOH$$_2$$
C. Used in Whitewashing      III. Na$$_2$$CO$$_3$$
D. Dentistry, ornamental work      IV. Mg$$^{2+}$$ ions

In the depression of freezing point experiment
A. Vapour pressure of the solution is less than that of pure solvent
B. Vapour pressure of the solution is more than that of pure solvent
C. Only solute molecules solidify at the freezing point
D. Only solvent molecules solidify at the freezing point

Statement I: For colloidal particles, the values of colligative properties are of small order as compared to values shown by true solutions at same concentration.
Statement II: For colloidal particles, the potential difference between the fixed layer and the diffused layer of same charges is called the electrokinetic potential or zeta potential.
In the light of the above statements, choose the correct answer from the options given below:

Match List I with List II.
List I      List II
A. Reverberatory furnace      I. Pig iron
B. Electrolytic cell      II. Aluminium
C. Blast furnace      III. Silicon
D. Zone refining furnace      IV. Copper

Assertion A: Hydrolysis of an alkyl chloride is a slow reaction but in the presence of NaI, the rate of hydrolysis increases.
Reason R: I$$^-$$ is a good nucleophile as well as a good leaving group.
In the light of the above statements, choose the correct answer from the options given below:

Given below are two statements:
Statement I: Noradrenaline is a neurotransmitter.
Statement II: Low level of noradrenaline is not the cause of depression in human.
In the light of the above statements, choose the correct answer from the options given below:

The dissociation constant of acetic is $$x \times 10^{-5}$$. When 25 mL of 0.2 M CH$$_3$$COONa solution is mixed with 25 mL of 0.02 M CH$$_3$$COOH solution, the pH of the resultant solution is found to be equal to 5. The value of $$x$$ is _____.

Backspace
789
456
123
0.-
Clear All

When Fe$$_{0.93}$$O is heated in presence of oxygen, it converts to Fe$$_2$$O$$_3$$. The number of correct statement/s from the following is _____.
A. The equivalent weight of Fe$$_{0.93}$$O is $$\frac{\text{Molecular weight}}{0.79}$$
B. The number of moles of Fe$$^{2+}$$ and Fe$$^{3+}$$ in 1 mole of Fe$$_{0.93}$$O is 0.79 and 0.14 respectively.
C. Fe$$_{0.93}$$O is metal deficient with lattice comprising of cubic closed packed arrangement of O$$^{2-}$$ ions.
D. The % composition of Fe$$^{2+}$$ and Fe$$^{3+}$$ in Fe$$_{0.93}$$O is 85% and 15% respectively.

Backspace
789
456
123
0.-
Clear All

5 g of NaOH was dissolved in deionized water to prepare a 450 mL stock solution. What volume (in mL) of this solution would be required to prepare 500 mL of 0.1 M solution? Given: Molar Mass of Na, O and H is 23, 16 and 1 g mol$$^{-1}$$ respectively

Backspace
789
456
123
0.-
Clear All

At 298 K, a 1 litre solution containing 10 mmol of Cr$$_2$$O$$_7^{2-}$$ and 100 mmol of Cr$$^{3+}$$ shows a pH of 3.0. Given: Cr$$_2$$O$$_7^{2-} \to$$ Cr$$^{3+}$$; E$$^0 = 1.330$$ V and $$\frac{2.303RT}{F} = 0.059$$ V. The potential for the half cell reaction is $$x \times 10^{-3}$$ V. The value of $$x$$ is _____.

Backspace
789
456
123
0.-
Clear All

The number of correct statement/s from the following is _____.
A. Larger the activation energy, smaller is the value of the rate constant.
B. The higher is the activation energy, higher is the value of the temperature coefficient.
C. At lower temperatures, increase in temperature causes more change in the value of k than at higher temperature.
D. A plot of ln k vs $$\frac{1}{T}$$ is a straight line with slope equal to $$\frac{-E_a}{R}$$

Backspace
789
456
123
0.-
Clear All