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NTA JEE Main 4th April 2015 Offline - Chemistry

For the following questions answer them individually

The molecular formula of a commercial resin used for exchanging ions in water softening is $$C_8H_7SO_3Na$$ (molecular weight = 206). What would be the maximum uptake of $$Ca^{2+}$$ ions by the resin if expressed in mol per gm?

The following reaction is performed at 298 K.
$$2NO(g) + O_2(g) \rightleftharpoons 2NO_2(g)$$
The standard free energy of the formation of $$NO(g)$$ is 86.6 kJ mol$$^{-1}$$ at 298 K. What is the standard free energy of the formation of $$NO_2(g)$$ at 298 K? $$(K_P = 1.6 \times 10^{12})$$

The standard Gibbs energy change at 300 K for the reaction $$2A \rightleftharpoons B + C$$ is 2494.2 J. At a given time, the composition of the reaction mixture is $$[A] = \frac{1}{2}$$, $$[B] = 2$$ and $$[C] = \frac{1}{2}$$. The reaction proceeds in the:
[R = 8.314 J/K-mol, e = 2.718] {Given antilog (-0.44) = 0.36}

From the following statements, choose the incorrect statement regarding $$H_2O_2$$.

Assertion: Nitrogen and Oxygen are the main components in the atmosphere but these do not react to form oxides of nitrogen.
Reason: The reaction between nitrogen and oxygen requires high temperature.

Sodium metal crystallizes in a body centred cubic lattice with a unit cell edge of 4.29 $$\mathring{A}$$. The radius of sodium atom is approximately:

The vapour pressure of acetone at 20$$^\circ$$C is 185 torr. When 1.2 g of a non-volatile substance was dissolved in 100 g of acetone at 20$$^\circ$$C, its vapour pressure was 183 torr. The molar mass (g mol$$^{-1}$$) of the substance is:

Higher order (>3) reactions are rare due to:

3 g of activated charcoal was added to 50 mL of acetic acid solution (0.06 N) in a flask. After an hour, it was filtered and the strength of the filtrate was found to be 0.042 N. The amount of acetic acid adsorbed (per gram of charcoal) is:

In the context of the Hall-Heroult process for the extraction of Al, which of the following statements is false?

Match the catalysts to the correct process.

Catalyst     Process
A. $$TiCl_3$$     i. Wacker process
B. $$PdCl_2$$     ii. Ziegler-Natta polymerisation
C. $$CuCl_2$$     iii. Contact process
D. $$V_2O_5$$     iv. Deacon's process

The colour of $$KMnO_4$$ is due to: [where M $$\rightarrow$$ metal, L $$\rightarrow$$ ligand]