Question 45

A voltaic cell is constructed as 

$$\text{Ni}(s) \mid \text{Ni}^{2+}(aq) \parallel \text{Ag}^+(aq) \mid \text{Ag}(s)$$

with $$E^\circ_{\text{Ni}^{2+}(aq)/\text{Ni}} = -0.236$$ V and $$E^\circ_{\text{Ag}^+(aq)/\text{Ag}} = 0.799$$ V. The initial concentration of $$\text{Ag}^+(aq)$$ in the silver half-cell is 0.005 M and the corresponding cell voltage is $$+0.95$$ V at 298 K. Identify the correct option from the following

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