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A carbonyl complex of Iridium with electronic configuration $$[\text{Xe}]\ 4f^{14}\ 5d^7\ 6s^2$$ and with the formula $$\text{IrCl(CO)(PPh}_3)_2$$ is known as Vaska$$'$$s complex. Which of the following ligand substitutions will decrease the triple bond character of CO in Vaska$$'$$s complex
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