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NTA JEE Main 9th April 2014 Online - Chemistry

For the following questions answer them individually

In the following sets of reactants which two sets best exhibit the amphoteric character of Al$$_2$$O$$_3$$ · xH$$_2$$O?
Set I: Al$$_2$$O$$_3$$ · xH$$_2$$O$$_{(s)}$$ + OH$$^-_{(aq)}$$
Set II: Al$$_2$$O$$_3$$x · H$$_2$$O$$_{(s)}$$ + H$$_2$$O$$_{(l)}$$
Set III: Al$$_2$$O$$_3$$x · H$$_2$$O$$_{(s)}$$ + H$$^+_{(aq)}$$
Set IV: Al$$_2$$O$$_3$$ · xH$$_2$$O$$_{(s)}$$ + NH$$_{3(aq)}$$

The number and type of bonds in C$$_2^{2-}$$ ion in CaC$$_2$$ are:

Van der Waal's equation for a gas is stated as, $$P = \frac{nRT}{V - nb} - a\left(\frac{n}{V}\right)^2$$. This equation reduces to the perfect gas equation, $$P = \frac{nRT}{V}$$ When,

The standard enthalpy of formation of NH$$_3$$ is $$-46.0$$ kJ/mol. If bond enthalpy of H$$_2$$ is $$-436$$ kJ/mol and that of N$$_2$$ is $$-712$$ kJ/mol, the average bond enthalpy of N$$-$$H bond in NH$$_3$$ is:

In a face centered cubic lattice atoms A are at the corner points and atoms B at the face centered points. If atom B is missing from one of the face centered points, the formula of the ionic compound is:

A current of 10.0 A flows for 2.00 h through an electrolytic cell containing a molten salt of metal X. This results in the decomposition of 0.250 mol of metal X at the cathode. The oxidation state of X in the molten salt is: (F = 96,500 C)

The standard electrode potentials ($$E^\circ_{M^{+}/M}$$) of four metals A, B, C and D are $$-1.2$$ V, 0.6 V, 0.85 V and $$-0.76$$ V, respectively. The sequence of deposition of metals on applying potential is:

The half-life period of a first-order reaction is 15 minutes. The amount of substance left after one hour will be:

The gas evolved on heating CaF$$_2$$ and SiO$$_2$$ with concentrated H$$_2$$SO$$_4$$, on hydrolysis gives a white gelatinous precipitate. The precipitate is:

The correct statement about the magnetic properties of [Fe(CN)$$_6$$]$$^{3-}$$ and [FeF$$_6$$]$$^{3-}$$ is: (Z = 26).

Allyl phenyl ether can be prepared by heating:

For the compounds CH$$_3$$Cl, CH$$_3$$Br, CH$$_3$$I and CH$$_3$$F, the correct order of increasing C-halogen bond length is:

In a nucleophilic substitution reaction: R $$-$$ Br + Cl$$^-$$ $$\xrightarrow{DMF}$$ R $$-$$ Cl + Br$$^-$$, which one of the following undergoes complete inversion of configuration?