NTA JEE Main 29th June 2022 Shift 1 - Chemistry

For the following questions answer them individually

Production of iron in blast furnace follows the following equation
Fe$$_3$$O$$_4$$(s) + 4CO(g) $$\rightarrow$$ 3Fe(l) + 4CO$$_2$$(g)
when 4.640 kg of Fe$$_3$$O$$_4$$ and 2.520 kg of CO are allowed to react then the amount of iron (in g) produced is:
[Given: Molar Atomic mass (g mol$$^{-1}$$): Fe = 56, O = 16, C = 12]

Which of the following statements are correct?
(A) The electronic configuration of Cr is [Ar] 3d$$^5$$4s$$^1$$.
(B) The magnetic quantum number may have a negative value.
(C) In the ground state of an atom, the orbitals are filled in order of their increasing energy order.
(D) The total number of nodes are given by n - 2.
Choose the most appropriate answer from the options given below.

Arrange the following in the decreasing order of their covalent character:
(A) LiCl
(B) NaCl
(C) KCl
(D) CsCl
Choose the most appropriate answer from the options given below

Which one of the following reactions indicates the reducing ability of hydrogen peroxide in basic medium?

Match List-I with Match List-II
List-I (Metal)              List-II (Emitted light wavelength (nm))
(A) Li                           (I)   670.8
(B) Na                         (II)  589.2
(C) Rb                         (III) 780.0
(D) Cs                         (V)  455.5
Choose the most appropriate answer from the options given below

Match List-I with Match List-II
List-I (Metal)               List-II (Application)
(A) Cs                    (I)    High temperature thermometer
(B) Ga                   (II)   Water repellent sprays
(C) B                     (III)  Photoelectric cells
(D) Si                    (V)   Bullet proof vest
Choose the most appropriate answer from the options given below

Two isomers 'A' and 'B' with molecular formula C$$_4$$H$$_8$$ give different products on oxidation with KMnO$$_4$$ in acidic medium. Isomer 'A' on reaction with KMnO$$_4$$/H$$^+$$ results in effervescence of a gas and gives ketone. The compound 'A' is

Which of the following is a correct statement?

Given below are two statements.
Statement I: Phenols are weakly acidic.
Statement II: Therefore they are freely soluble in NaOH solution and are weaker acids than alcohols and water.
Choose the most appropriate option

Given below are two statements:
Statement I: The esterification of carboxylic acid with an alcohol is a nucleophilic acyl substitution.
Statement II: Electron withdrawing groups in the carboxylic acid will increase the rate of esterification reaction.
Choose the most appropriate option

Sugar moiety in DNA and RNA molecules respectively are

Geraniol, a volatile organic compound, is a component of rose oil. The density of the vapour is 0.46 gL$$^{-1}$$ at 257°C and 100 mmHg. The molar mass of geraniol is ______ (Nearest Integer)
[Given R = 0.082 L atm K$$^{-1}$$ mol$$^{-1}$$]

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17.0 g of NH$$_3$$ completely vapourises at $$-33.42$$°C and 1 bar pressure and the enthalpy change in the process is 23.4 kJ mol$$^{-1}$$. The enthalpy change for the vapourisation of 85 g of NH$$_3$$ under the same conditions is ______ kJ.

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Kjeldahl's method was used for the estimation of nitrogen in an organic compound. The ammonia evolved from 0.55 g of the compound neutralised 12.5 mL of 1M H$$_2$$SO$$_4$$ solution. The percentage of nitrogen in the compound is ______ (Nearest Integer)

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1.2 mL of acetic acid is dissolved in water to make 2.0 L of solution. The depression in freezing point observed for this strength of acid is 0.0198°C. The percentage of dissociation of the acid is ______ (Nearest integer)
[Given: Density of acetic acid is 1.02 g mL$$^{-1}$$ Molar mass of acetic acid is 60 g mol$$^{-1}$$, K$$_f$$(H$$_2$$O) = 1.85 K kg mol$$^{-1}$$]

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A dilute solution of sulphuric acid is electrolysed using a current of 0.10 A for 2 hours to produce hydrogen and oxygen gas. The total volume of gases produced at STP is ______ cm$$^3$$. (Nearest integer) [Given: Faraday constant F = 96500 C mol$$^{-1}$$ at STP, molar volume of an ideal gas is 22.7 L mol$$^{-1}$$]

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The activation energy of one of the reactions in a biochemical process is 532611 J mol$$^{-1}$$. When the temperature falls from 310 K to 300 K, the change in rate constant observed is k$$_{300}$$ = x $$\times$$ 10$$^{-3}$$k$$_{310}$$. The value of x is ______.
[Given: ln 10 = 2.3 R = 8.3 J K$$^{-1}$$ mol$$^{-1}$$]

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The number of terminal oxygen atoms present in the product B obtained from the following reaction is ______.
FeCr$$_2$$O$$_4$$ + Na$$_2$$CO$$_3$$ + O$$_2$$ $$\rightarrow$$ A + Fe$$_2$$O$$_3$$ + CO$$_2$$
A + H$$^+$$ $$\rightarrow$$ B + H$$_2$$O + Na$$^+$$

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An acidified manganate solution undergoes disproportionation reaction. The spin-only magnetic moment value of the product having manganese in higher oxidation state is ______ B.M. (Nearest integer)

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