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NTA JEE Main 25th June 2022 Shift 1 - Chemistry

For the following questions answer them individually

Bonding in which of the following diatomic molecule(s) become(s) stronger, on the basis of MO Theory, by removal of an electron?
(A) NO
(B) $$N_2$$
(C) $$O_2$$
(D) $$C_2$$
(E) $$B_2$$
Choose the most appropriate answer from the options given below :

Incorrect statement for Tyndall effect is

Leaching of gold with dilute aqueous solution of NaCN in presence of oxygen gives complex A, which on reaction with zinc forms the elemental gold and another complex B. A and B, respectively are

Cerium IV has a noble gas configuration. Which of the following is the correct statement about it?

Using very little soap while washing clothes, does not serve the purpose of cleaning of clothes, because

$$1$$ L aqueous solution of $$H_2SO_4$$ contains $$0.02$$ m mol $$H_2SO_4$$. $$50\%$$ of this solution is diluted with deionized water to give $$1$$ L solution A. In solution A, $$0.01$$ m mol of $$H_2SO_4$$ are added. Total m mols of $$H_2SO_4$$ in the final solution is ______ $$\times 10^{-3}$$ m moles.

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The longest wavelength of light that can be used for the ionisation of lithium ion $$Li^{2+}$$ is $$x \times 10^{-8}$$ m. The value of $$x$$ is ______ (Nearest Integer)
(Given : Energy of the electron in the first shell of the hydrogen atom is $$-2.2 \times 10^{-18}$$ J; $$h = 6.63 \times 10^{-34}$$ Js and $$c = 3 \times 10^{8}$$ ms$$^{-1}$$)

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The standard entropy change for the reaction
$$4Fe(s) + 3O_2(g) \to 2Fe_2O_3(s)$$ is $$-550$$ J K$$^{-1}$$ at $$298$$ K
[Given : The standard enthalpy change for the reaction is $$-165$$ kJ mol$$^{-1}$$]. The temperature in K at which the reaction attains equilibrium is (Nearest Integer) ______

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The standard free energy change $$\Delta G°$$ for $$50\%$$ dissociation of $$N_2O_4$$ into $$NO_2$$ at $$27°$$C and $$1$$ atm pressure is $$-x$$ J mol$$^{-1}$$. The value of $$x$$ is ______ J. (Nearest Integer)
[Given : $$R = 8.31$$ J K$$^{-1}$$ mol$$^{-1}$$, $$\log 1.33 = 0.1239$$, $$\ln 10 = 2.3$$]

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The distance between $$Na^+$$ and $$Cl^-$$ ions in solid NaCl of density $$43.1$$ g cm$$^{-3}$$ is ______ $$\times 10^{-10}$$ m. (Nearest Integer)
(Given : $$N_A = 6.02 \times 10^{23}$$ mol$$^{-1}$$)

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In a cell, the following reactions take place
$$Fe^{2+} \to Fe^{3+} + e^-$$ $$E^\circ_{Fe^{3+}/Fe^{2+}} = 0.77$$ V
$$2I^- \to I_2 + 2e^-$$ $$E^\circ_{I_2/I^-} = 0.54$$ V
The standard electrode potential for the spontaneous reaction in the cell is $$x \times 10^{-2}$$ V at $$298$$ K. The value of $$x$$ is ______ (Nearest Integer)

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For a given chemical reaction $$\gamma_1 A + \gamma_2 B \to \gamma_3 C + \gamma_4 D$$. Concentration of C changes from $$10$$ mmol dm$$^{-3}$$ to $$20$$ mmol dm$$^{-3}$$ in $$10$$ s. Rate of appearance of D is $$1.5$$ times the rate of disappearance of B which is twice the rate of disappearance of A. The rate of appearance of D has been experimentally determined to be $$9$$ mmol dm$$^{-3}$$ s$$^{-1}$$. Therefore the rate of reaction is ______ mmol dm$$^{-3}$$ s$$^{-1}$$. (Nearest Integer)

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If $$[CuH_2O_4]^{2+}$$ absorbs a light of wavelength $$600$$ nm for d-d transition, then the value of octahedral crystal field splitting energy for $$[CuH_2O_6]^{2+}$$ will be ______ $$\times 10^{-21}$$ J [Nearest integer]
(Given : $$h = 6.63 \times 10^{-34}$$ Js and $$c = 3.08 \times 10^{8}$$ ms$$^{-1}$$)

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