NTA JEE Main 25th June 2022 Shift 1 - Chemistry

The pair, in which ions are isoelectronic with $$Al^{3+}$$ is

Bonding in which of the following diatomic molecule(s) become(s) stronger, on the basis of MO Theory, by removal of an electron?
(A) NO
(B) $$N_2$$
(C) $$O_2$$
(D) $$C_2$$
(E) $$B_2$$
Choose the most appropriate answer from the options given below :

Number of electron deficient molecules among the following $$PH_3, B_2H_6, CCl_4, NH_3, LiH$$ and $$BCl_3$$ is

Which one of the following alkaline earth metal ions has the highest ionic mobility in its aqueous solution?

Phenol on reaction with dilute nitric acid, gives two products. Which method will be most efficient for large scale separation?

In the following structures, which one is having staggered conformation with maximum dihedral angle?

The IUPAC name of ethylidene chloride is

The product formed in the following reaction.

is:

The eutrophication of water body results in

Incorrect statement for Tyndall effect is

Leaching of gold with dilute aqueous solution of NaCN in presence of oxygen gives complex A, which on reaction with zinc forms the elemental gold and another complex B. A and B, respectively are

Cerium IV has a noble gas configuration. Which of the following is the correct statement about it?

Among the following, which is the strongest oxidizing agent?

White precipitate of AgCl dissolves in aqueous ammonia solution due to formation of

The major product in the reaction

The intermediate X, in the reaction

In the following reaction :

The compounds A and B respectively are

The reaction of 

with bromine and KOH gives $$RNH_2$$ as the end product. Which one of the following is the intermediate product formed in this reaction?

Using very little soap while washing clothes, does not serve the purpose of cleaning of clothes, because

Which one of the following is an example of artificial sweetner?

The number of N atoms in $$681$$ g of $$C_7H_5N_3O_6$$ is $$x \times 10^{21}$$. The value of $$x$$ is ______ (Nearest Integer)
$$N_A = 6.02 \times 10^{23}$$ mol$$^{-1}$$

$$1$$ L aqueous solution of $$H_2SO_4$$ contains $$0.02$$ m mol $$H_2SO_4$$. $$50\%$$ of this solution is diluted with deionized water to give $$1$$ L solution A. In solution A, $$0.01$$ m mol of $$H_2SO_4$$ are added. Total m mols of $$H_2SO_4$$ in the final solution is ______ $$\times 10^{-3}$$ m moles.

Number of grams of bromine that will completely react with $$5.0$$ g of pent-1-ene is ______ $$\times 10^{-2}$$ g. (Atomic mass of Br $$= 80$$ g/mol) [Nearest integer]

The longest wavelength of light that can be used for the ionisation of lithium ion $$Li^{2+}$$ is $$x \times 10^{-8}$$ m. The value of $$x$$ is ______ (Nearest Integer)
(Given : Energy of the electron in the first shell of the hydrogen atom is $$-2.2 \times 10^{-18}$$ J; $$h = 6.63 \times 10^{-34}$$ Js and $$c = 3 \times 10^{8}$$ ms$$^{-1}$$)

The standard entropy change for the reaction
$$4Fe(s) + 3O_2(g) \to 2Fe_2O_3(s)$$ is $$-550$$ J K$$^{-1}$$ at $$298$$ K
[Given : The standard enthalpy change for the reaction is $$-165$$ kJ mol$$^{-1}$$]. The temperature in K at which the reaction attains equilibrium is (Nearest Integer) ______

The standard free energy change $$\Delta G°$$ for $$50\%$$ dissociation of $$N_2O_4$$ into $$NO_2$$ at $$27°$$C and $$1$$ atm pressure is $$-x$$ J mol$$^{-1}$$. The value of $$x$$ is ______ J. (Nearest Integer)
[Given : $$R = 8.31$$ J K$$^{-1}$$ mol$$^{-1}$$, $$\log 1.33 = 0.1239$$, $$\ln 10 = 2.3$$]

The distance between $$Na^+$$ and $$Cl^-$$ ions in solid NaCl of density $$43.1$$ g cm$$^{-3}$$ is ______ $$\times 10^{-10}$$ m. (Nearest Integer)
(Given : $$N_A = 6.02 \times 10^{23}$$ mol$$^{-1}$$)

In a cell, the following reactions take place
$$Fe^{2+} \to Fe^{3+} + e^-$$ $$E^\circ_{Fe^{3+}/Fe^{2+}} = 0.77$$ V
$$2I^- \to I_2 + 2e^-$$ $$E^\circ_{I_2/I^-} = 0.54$$ V
The standard electrode potential for the spontaneous reaction in the cell is $$x \times 10^{-2}$$ V at $$298$$ K. The value of $$x$$ is ______ (Nearest Integer)

For a given chemical reaction $$\gamma_1 A + \gamma_2 B \to \gamma_3 C + \gamma_4 D$$. Concentration of C changes from $$10$$ mmol dm$$^{-3}$$ to $$20$$ mmol dm$$^{-3}$$ in $$10$$ s. Rate of appearance of D is $$1.5$$ times the rate of disappearance of B which is twice the rate of disappearance of A. The rate of appearance of D has been experimentally determined to be $$9$$ mmol dm$$^{-3}$$ s$$^{-1}$$. Therefore the rate of reaction is ______ mmol dm$$^{-3}$$ s$$^{-1}$$. (Nearest Integer)

If $$[CuH_2O_4]^{2+}$$ absorbs a light of wavelength $$600$$ nm for d-d transition, then the value of octahedral crystal field splitting energy for $$[CuH_2O_6]^{2+}$$ will be ______ $$\times 10^{-21}$$ J [Nearest integer]
(Given : $$h = 6.63 \times 10^{-34}$$ Js and $$c = 3.08 \times 10^{8}$$ ms$$^{-1}$$)