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NTA JEE Main 13th April 2023 Shift 2 - Chemistry Section B

For the following questions answer them individually

Sea water contains $$29.25$$% NaCl and $$19$$% MgCl$$_2$$ by weight of solution. The normal boiling point of the sea water is _____ °C (Nearest integer) Assume 100% ionization for both NaCl and MgCl$$_2$$. Given:
K$$_b$$H$$_2$$O $$= 0.52$$ K kg mol$$^{-1}$$. Molar mass of NaCl and MgCl$$_2$$ is $$58.5$$ and $$95$$ g mol$$^{-1}$$ respectively.

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At 298 K, the standard reduction potential for Cu$$^{2+}$$/Cu electrode is 0.34 V. Given :
K$$_{sp}$$Cu(OH)$$_2$$ $$= 1 \times 10^{-20}$$. Take $$\frac{2.303RT}{F} = 0.059$$ V. The reduction potential at pH = 14 for the above couple is $$(-) x \times 10^{-2}$$ V. The value of x is _____.

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A(g) $$\to$$ 2B(g) + C(g) is a first order reaction. The initial pressure of the system was found to be $$800$$ mm Hg which increased to $$1600$$ mm Hg after $$10$$ min. The total pressure of the system after $$30$$ min will be _____ mm Hg. (Nearest integer)

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