JEE (Advanced) 2009 Paper-2

Instructions

Each question contains statements given in two columns, which have to be matched. The statements in ColumnI are labelled A, B, C and D, while the statements in Column II are labelled p, q, r, s and t. Any given statement in Column I can have correct matching with ONE OR MORE statement(s) in Column II. The appropriate bubbles corresponding to the answers to these questions have to be darkened as illustrated in the following example: If the correct matches are A p, s and t; B — q and r; C p and q; and D —s and t; then the correct darkening of bubbles will look like the following.

Question 11

Match each of the compounds given in Column I with the reaction(s), that they can undergo, given in Column II.

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Instructions

For the following questions answer them individually

Question 12

In a constant volume calorimeter, 3.5 g of a gas with molecular weight 28 was burnt in excess oxygen at 298.0 K. The temperature of the calorimeter was found to increase from 298.0 K to 298.45 K due to the combustion process. Given that the heat capacity of the calorimeteris 2.5 kJ K$$^{-1}$$, the numerical value for the enthalpy of combustion of the gas in kJ mol$$^{-1}$$ is

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Question 13

At 400 K, the root mean square (rms) speed of a gas X (molecular weight = 40) is equal to the most probable speed of gas Y at 60K. The molecular weight of the gas Y is

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Question 14

The dissociation constant of a substituted benzoic acid at $$25^\circ C$$ is $$1.0 \times 10^{-4}$$. The pH of a 0.01 M solutionofits sodium salt is

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Question 15

The total number of $$\alpha$$ and $$\beta$$ particles emitted in the nuclear reaction $$_{92}^{238}U \rightarrow _{82}^{214}Pb$$ is

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Question 16

The oxidation number of Mnin the product of alkaline oxidative fusion of $$MnO_2$$ is

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Question 17

The number of water molecule(s) directly bonded to the metal centre in $$CuSO_4.5H_2O$$ is

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Question 18

The coordination numberof Al in the crystalline state of $$AlCl_3$$, is

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Question 19

The total number of cyclic structural as well as stereo isomers possible for a compound with the molecular formula $$C_5H_{10}$$ is

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Question 20

If the sum of first n terms of an A.P. is $$cn^2$$, then the sum of squares of these n terms is

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