JEE (Advanced) 2007 Paper-1

Instructions

For the following questions answer them individually

Question 31

The value of $$\log_{10} K$$ for a reaction $$A \rightleftharpoons B$$ is
(Given : $$\triangle_rH_{298K}^{\circ}$$ = -54.07 kJ mol$$^{-1}$$, $$\triangle_rS_{298K}^{\circ}$$ = 10 JK$$^{-1}$$ mol$$^{-1}$$ and R = 8.314 JK$$^{-1}$$ mol$$^{-1}$$; $$2.303 \times 8.314 \times 298 = 5705$$)

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Question 32

STATEMENT-1 : Boron always forms covalent bond.
because
STATEMENT-2: The small size of $$B^{3+}$$ favours formation of covalent bond.

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Question 33

STATEMENT-1: In water, orthoboric acid behaves as a weak monobasic acid.
because
STATEMENT-2: In water, orthoboric acid acts as a proton donor.

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Question 34

STATEMENT-1: p-Hydroxybenzoic acid has a lower boiling point than o-hydroxybenzoic acid.
because
STATEMENT-2 : o-Hydroxybenzoic acid has intramolecular hydrogen bonding.

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Question 35

STATEMENT-1 : Micelles are formed by surfactant molecules above the critical micellar concentration (CMC).
because
STATEMENT-2 : The conductivity of a solution having surfactant molecules decreases sharply at the CMC.

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Question 36

Argon is used in are welding because of its

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Question 37

The structure of $$XeO_3$$ is

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Question 38

$$XeF_4$$ and $$XeF_6$$ are expected to be

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Instructions

Chemical reactions involve interaction of atoms and molecules. A large number of atoms/molecules (approximately $$6.023 \times 10^{23}$$) are present in a few grams of any chemical compound varying with their atomic/molecular masses. To handle such large numbers conveniently, the mole concept was introduced. This concept has implications in diverse areas such as analytical chemistry, biochemistry, electrochemistry and radiochemistry. The following exampleillustrates a typical case, involving chemical/electrochemical reaction, which requires a clear understanding of the mole concept.

A 4.0 molar aqueous solution of NaCl is prepared and 500 mLofthis solution is electrolysed. This leads to the evolution of chlorine gas at one of the electrodes
(atomic mass : Na = 23, Hg = 200; 1 Faraday = 96500 coulombs).

Question 39

The total number of moles of chlorine gas evolved is

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Question 40

If the cathode is a Hg electrode, the maximum weight (g) of amalgam formed from this solution is

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