Question 83

A white sodium salt dissolves readily in water to give a solution neutral to litmus. A silver nitrate solution is added to the above solution white ppt is formed which does not dissolve in dil. nitric acid. The anion is

Solution

A neutral solution rules out $$\text{Na}_2\text{CO}_3$$ and $$\text{Na}_2\text{S}$$, which are basic, and $$\text{Ag}_2\text{S}$$ would be black anyway. The white precipitate insoluble in dilute nitric acid is AgCl, so the salt is NaCl and the anion is $$\text{Cl}^-$$.

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