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For which of the following situations, zeroth law of thermodynamics will not be applicable?
50 cc of water at $$25^\circ C$$ is mixed with 150 cc of water at $$25^\circ C$$
500 cc of milk at $$15^\circ C$$ is mixed with 100 cc of water at $$15^\circ C$$
5 kg of wet steam at $$100^\circ C$$ is mixed with 50 kg of dry and saturated Steam at $$100^\circ C$$
10 cc of water at $$20^\circ C$$ is mixed with 10 cc of sulphuric acid at $$20^\circ C$$
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