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Question 42

Maleic acid and fumaric acids are

Solution

Maleic acid and fumaric acid are two different arrangements of the same molecular formula $$C_4H_4O_4$$ (the structure of $$HOOC - CH = CH - COOH$$).

Because the C=C double bond cannot freely rotate, the two $$-COOH$$ groups can be located either on the same side of the double bond (cis) or on opposite sides (trans).

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This difference arises purely from restricted rotation about the double bond, not from any change in carbon chain, functional group, or tautomeric shift. Hence they are classified as geometrical (cis-trans) isomers.

Therefore, the correct choice is:
Option D which is: Geometrical isomers

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