Question 27

An electrochemical cell was constructed with $$\text{Fe}^{2+}$$/Fe and $$\text{Cd}^{2+}$$/Cd at $$25^\circ\text{C}$$ with initial concentrations of $$[\text{Fe}^{2+}]$$ = 0.800 M and $$[\text{Cd}^{2+}]$$ = 0.250 M. The EMF of the cell when $$[\text{Cd}^{2+}]$$ becomes 0.100 M is

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