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Heat of reaction and heat of formation will be the same in
I. $$\frac{1}{2}\text{N}_2(g) + \text{O}_2(g) \rightarrow \text{NO}_2(g)$$,
II. $$\text{Xe}(g) + 2\text{F}_2(g) \rightarrow \text{XeF}_4(g)$$,
III. $$\text{N}_2(g) + \text{O}_3(g) \rightarrow \text{N}_2\text{O}_3(g)$$,
IV. $$\text{C (diamond)} + \text{O}_2(g) \rightarrow \text{CO}_2(g)$$
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