Join WhatsApp Icon JEE WhatsApp Group

NTA JEE Main 9th January 2019 Shift 2 - Chemistry

For the following questions answer them individually

Which of the following combination of statements is true regarding the interpretation of the atomic orbitals?
(A) An electron in an orbital of high angular momentum stays away from the nucleus than an electron in the orbital of lower angular momentum.
(B) For a given value of the principal quantum number, the size of the orbit is inversely proportional to the azimuthal quantum number.
(C) According to wave mechanics, the ground state angular momentum is equal to $$\frac{h}{2\pi}$$.
(D) The plot of $$\psi$$ Vs $$r$$ for various azimuthal quantum numbers, shows peak shifting towards higher $$r$$ value.

The entropy change associated with the conversion of 1 kg of ice at 273 K to water vapours at 383 K is: (Specific heat of water liquid and water vapour are 4.2 kJ K$$^{-1}$$ and 2.0 kJ K$$^{-1}$$ kg$$^{-1}$$; heat of liquid fusion and vaporization of water are 334 kJ kg$$^{-1}$$ and 2491 kJ kg$$^{-1}$$, respectively). (log 273 = 2.436, log 373 = 2.572, log 383 = 2.583)

At 100$$^{\circ}$$C, copper (Cu) has FCC unit cell structure with cell edge length of $$x$$ $$\text{Å}$$. What is the approximate density of Cu (in g cm$$^{-3}$$) at this temperature? [Atomic Mass of Cu = 63.55 u]

If the standard electrode potential for a cell is 2 V at 300 K, the equilibrium constant (K) for the reaction.
$$Zn(s) + Cu^{2+}(aq) \rightleftharpoons Zn^{2+}(aq) + Cu(s)$$
at 300 K is approximately: ($$R = 8$$ J K$$^{-1}$$ mol$$^{-1}$$, $$F = 96000$$ C mol$$^{-1}$$)

For the reaction, $$2A + B \rightarrow$$ products, when the concentration of $$A$$ and $$B$$ both were doubled, the rate of the reaction increased from 0.3 mol L$$^{-1}$$ s$$^{-1}$$ to 2.4 mol L$$^{-1}$$ s$$^{-1}$$. When the concentration of $$A$$ alone is doubled, the rate increased from 0.3 mol L$$^{-1}$$ s$$^{-1}$$ to 0.6 mol L$$^{-1}$$ s$$^{-1}$$. Which one of the following statements is correct?

Consider the following reversible chemical reactions:
$$A_2(g) + B_2(g) \stackrel{k_1}{\rightleftharpoons} 2AB(g) \ldots (1)$$ 
$$6AB(g) \stackrel{k_2}{\rightleftharpoons} 3A_2(g) + 3B_2(g) \ldots (2)$$ 
The relation between $$K_1$$ and $$K_2$$ is:

The correct match between Item I and Item II is:
Item I                        Item II
(A) Benzaldehyde      (P) Mobile phase
(B) Alumina               (Q) Adsorbent
(C) Acetonitrile         (R) Adsorbate

The correct statement regarding the given Ellingham diagram is:

Homoleptic octahedral complexes of a metal ion $$M^{3+}$$ with three monodentate ligands $$L_1$$, $$L_2$$ and $$L_3$$ absorb wavelengths in the region of green, blue and red respectively. The increasing order of the ligand strength is:

The test performed on compound x and their inferences are:
Test                                             Inference
(a) 2,4-DNP test                    Coloured precipitate yellow
(b) Iodoform test                  Yellow precipitate
(c) Azo-dye test                    No dye formation
Compound 'x' is: