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NTA JEE Main 9th April 2013 Online - Chemistry

For the following questions answer them individually

Electron gain enthalpy with negative sign of fluorine is less than that of chlorine due to :

In which of the following ionization processes the bond energy has increased and also the magnetic behaviour has changed from paramagnetic to diamagnetic?

Given: (I) $$H_2(g) + \frac{1}{2}O_2(g) \rightarrow H_2O(l)$$; $$\Delta H°_{298K} = -285.9$$ kJ mol$$^{-1}$$
(II) $$H_2(g) + \frac{1}{2}O_2(g) \rightarrow H_2O(g)$$; $$\Delta H°_{298K} = -241.8$$ kJ mol$$^{-1}$$
The molar enthalpy of vapourisation of water will be :

Solid $$Ba(NO_3)_2$$ is gradually dissolved in a $$1.0 \times 10^{-4}$$ M $$Na_2CO_3$$ solution. At which concentration of $$Ba^{2+}$$, precipitate of $$BaCO_3$$ begins to form? ($$K_{sp}$$ for $$BaCO_3 = 5.1 \times 10^{-9}$$)

Sodium Carbonate cannot be used in place of $$(NH_4)_2CO_3$$ for the identification of $$Ca^{2+}$$, $$Ba^{2+}$$ and $$Sr^{2+}$$ ions (in group V) during mixture analysis because :

The addition of HI in the presence of peroxide catalyst does not follow anti-Markovnikov's rule because :

Electrode potentials (E°) are given below :
$$Cu^+/Cu = +0.52$$ V,
$$Fe^{3+}/Fe^{2+} = +0.77$$ V,
$$\frac{1}{2}I_2(s)/I^- = +0.54$$ V,
$$Ag^+/Ag = +0.88$$ V.
Based on the above potentials, strongest oxidizing agent will be :

The instantaneous rate of disappearance of $$MnO_4^-$$ ion in the following reaction is $$4.56 \times 10^{-3}$$ Ms$$^{-1}$$
$$2MnO_4^- + 10I^- + 16H^+ \rightarrow 2Mn^{2+} + 5I_2 + 8H_2O$$
The rate of appearance of $$I_2$$ is :

Calcination is the process in which:

An ether (A), $$C_5H_{12}O$$, when heated with excess of hot concentrated HI produced two alkyl halides which when treated with NaOH yielded compounds (B) and (C). Oxidation of (B) and (C) gave a propanone and an ethanoic acid respectively. The IUPAC name of the ether (A) is :