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NTA JEE Main 26th July 2022 Shift 1 - Chemistry

For the following questions answer them individually

Given two statements below:
Statement I: In $$Cl_2$$ molecule the covalent radius is double of the atomic radius of chlorine.
Statement II: Radius of anionic species is always greater than their parent atomic radius.
Choose the most appropriate answer from options given below

Reaction of $$BeCl_2$$ with $$LiAlH_4$$ gives:
(A) $$AlCl_3$$
(B) $$BeH_2$$
(C) $$LiH$$
(D) $$LiCl$$
(E) $$BeAlH_4$$
Choose the correct answer from options given below

Which technique among the following, is most appropriate in separation of a mixture of $$100 \text{ mg}$$ of $$p$$-nitrophenol and picric acid?

Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R).
Assertion (A):
Experimental reaction of $$CH_3Cl$$ with aniline and anhydrous $$AlCl_3$$ does not give $$o$$ and $$p$$-methylaniline.
Reason (R): The $$-NH_2$$ group of aniline becomes deactivating because of salt formation with anhydrous $$AlCl_3$$ and hence yields $$m$$-methyl aniline as the product.
In the light of the above statements, choose the most appropriate answer from the options given below

Chlorophyll extracted from the crushed green leaves was dissolved in water to make $$2 \text{ L}$$ solution of Mg of concentration $$48 \text{ ppm}$$. The number of atoms of Mg in this solution is $$x \times 10^{20}$$ atoms. The value of $$x$$ is ______ (Nearest Integer) (Given: Atomic mass of Mg is $$24 \text{ g mol}^{-1}$$, $$N_A = 6.02 \times 10^{23} \text{ mol}^{-1}$$)

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When $$800 \text{ mL}$$ of $$0.5M$$ nitric acid is heated in a beaker, its volume is reduced to half and $$11.5 \text{ g}$$ of nitric acid is evaporated. The molarity of the remaining nitric acid solution is $$x \times 10^{-2} \text{ M}$$. (Molar mass of nitric acid is $$63 \text{ g mol}^{-1}$$)

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The wavelength of an electron and a neutron will become equal when the velocity of the electron is $$x$$ times the velocity of neutron. The value of $$x$$ is ______ (the nearest integer) (Mass of electron is $$9.1 \times 10^{-31} \text{ kg}$$ and mass of neutron is $$1.6 \times 10^{-27} \text{ kg}$$)

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$$2.4 \text{ g}$$ coal is burnt in a bomb calorimeter in excess of oxygen at $$298 \text{ K}$$ and $$1 \text{ atm}$$ pressure. The temperature of the calorimeter rises from $$298 \text{ K}$$ to $$300 \text{ K}$$. The enthalpy change during the combustion of coal is $$-x \text{ kJ mol}^{-1}$$. The value of $$x$$ is ______ (Given: Heat capacity of bomb calorimeter $$20.0 \text{ kJ K}^{-1}$$. Assume coal to be pure carbon)

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At $$298 \text{ K}$$, the equilibrium constant is $$2 \times 10^{15}$$ for the reaction:
$$Cu(s) + 2Ag^+(aq) \rightleftharpoons Cu^{2+}(aq) + 2Ag(s)$$
The equilibrium constant for the reaction
$$\dfrac{1}{2}Cu^{2+}(aq) + Ag(s) \rightleftharpoons \dfrac{1}{2}Cu(s) + Ag^+(aq)$$
is $$x \times 10^{-8}$$. The value of $$x$$ is ______.

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