Sign in
Please select an account to continue using cracku.in
↓ →
Join Our JEE Preparation Group
Prep with like-minded aspirants; Get access to free daily tests and study material.
The amount of charge in F (Faraday) required to obtain one mole of iron from $$Fe_3O_4$$ is ______. (Round off to the nearest integer)
Correct Answer: 3
In $$\mathrm{Fe_3O_4}$$, the oxidation state of oxygen is:
$$\mathrm{O = -2}$$
Let the average oxidation state of iron be $$\mathrm{x}$$.
For a neutral compound:
$$\mathrm{3x + 4(-2) = 0}$$
$$\mathrm{3x - 8 = 0}$$
$$\mathrm{3x = 8}$$
$$\mathrm{x = +\frac{8}{3}}$$
Thus, iron is reduced from $$\mathrm{+\frac{8}{3}}$$ to $$\mathrm{0}$$.
For one mole of $$\mathrm{Fe_3O_4}$$:
$$\mathrm{3\ Fe^{+\frac{8}{3}} \longrightarrow 3\ Fe^0}$$
Total electrons required:
$$\mathrm{3\times\frac{8}{3} = 8\ mol\ e^-}$$
Since:
$$\mathrm{1\ mol\ e^- = 1\ F}$$
Charge required for producing $$\mathrm{3\ mol}$$ of iron:
$$\mathrm{= 8\ F}$$
Therefore, charge required for producing $$\mathrm{1\ mol}$$ of iron:
$$\mathrm{= \frac{8}{3}\ F}$$
$$\mathrm{= 2.667\ F}$$
Rounding to nearest integer:
$$\boxed{\mathrm{3}}$$
Click on the Email ☝️ to Watch the Video Solution
Create a FREE account and get:
Educational materials for JEE preparation