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NTA JEE Main 25th July 2022 Shift 1 - Chemistry

For the following questions answer them individually

$$SO_2Cl_2$$ on reaction with excess of water results into acidic mixture
$$SO_2Cl_2 + 2H_2O \rightarrow H_2SO_4 + 2HCl$$
16 moles of $$NaOH$$ is required for the complete neutralisation of the resultant acidic mixture. The number of moles of $$SO_2Cl_2$$ used is

Which of the following sets of quantum numbers is not allowed?

$$20 \text{ mL}$$ of $$0.1 \text{ M } NH_4OH$$ is mixed with $$40 \text{ mL}$$ of $$0.05 \text{ M HCl}$$. The pH of the mixture is nearest to:
(Given: $$K_b(NH_4OH) = 1 \times 10^{-5}$$, $$\log 2 = 0.30$$, $$\log 3 = 0.48$$, $$\log 5 = 0.69$$, $$\log 7 = 0.84$$, $$\log 11 = 1.04$$)

A compound 'A' on reaction with 'X' and 'Y' produces the same major product but different by-products 'a' and 'b'. Oxidation of 'a' gives a substance produced by ants.

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'X' and 'Y' respectively are

The depression in freezing point observed for a formic acid solution of concentration $$0.5 \text{ mL L}^{-1}$$ is $$0.0405°C$$. Density of formic acid is $$1.05 \text{ g mL}^{-1}$$. The Van't Hoff factor of the formic acid solution is nearly: (Given for water $$K_f = 1.86 \text{ K kg mol}^{-1}$$)

The compound(s) that is(are) removed as slag during the extraction of copper is:
(1) CaO
(2) FeO
(3) Al₂O₃
(4) ZnO
(5) NiO
Choose the correct answer from the options given below

Given below are two statements:
Statement I: On heating with $$KHSO_4$$, glycerol is dehydrated and acrolein is formed.
Statement II: Acrolein has fruity odour and can be used to test glycerol's presence.
Choose the correct option.

An organic compound 'A' on reaction with $$NH_3$$ followed by heating gives compound B. Which on further strong heating gives compound C ($$C_8H_5NO_2$$). Compound C on sequential reaction with ethanolic KOH, alkyl chloride and hydrolysis with alkali gives a primary amine. The compound A is

The pressure of a moist gas at $$27°C$$ is $$4 \text{ atm}$$. The volume of the container is doubled at the same temperature. The new pressure of the moist gas is ______ $$\times 10^{-1}$$ atm. (Nearest integer)
(Given: The vapour pressure of water at $$27°C$$ is $$0.4 \text{ atm}$$)

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The enthalpy of combustion of propane, graphite and dihydrogen at $$298 \text{ K}$$ are: $$-2220.0 \text{ kJ mol}^{-1}$$, $$-393.5 \text{ kJ mol}^{-1}$$ and $$-285.8 \text{ kJ mol}^{-1}$$ respectively. The magnitude of enthalpy of formation of propane ($$C_3H_8$$) is ______ $$\text{kJ mol}^{-1}$$. (Nearest integer)

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While estimating the nitrogen present in an organic compound by Kjeldahl's method, the ammonia evolved from $$0.25 \text{ g}$$ of the compound neutralized $$2.5 \text{ mL}$$ of $$2M \text{ } H_2SO_4$$. The percentage of nitrogen present in organic compound is ______.

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The cell potential for $$Zn | Zn^{2+}(aq) || Sn^{x+} | Sn$$ is $$0.801 \text{ V}$$ at $$298 \text{ K}$$. The reaction quotient for the above reaction is $$10^{-2}$$. The number of electrons involved in the given electrochemical cell reaction is ______.
(Given $$E^0_{Zn^{2+}|Zn} = -0.763 \text{ V}$$, $$E^0_{Sn^{x+}|Sn} = +0.008 \text{ V}$$ and $$\dfrac{2.303RT}{F} = 0.06 \text{ V}$$)

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The half life for the decomposition of gaseous compound A is $$240 \text{ s}$$ when the gaseous pressure was $$500 \text{ Torr}$$ initially. When the pressure was $$250 \text{ Torr}$$, the half life was found to be $$4.0 \text{ min}$$. The order of the reaction is ______ (Nearest integer).

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Consider the following metal complexes:
$$[Co(NH_3)]^{3+}$$
$$[CoCl(NH_3)_5]^{2+}$$
$$[Co(CN)_6]^{3-}$$
$$[Co(NH_3)_5(H_2O)]^{3+}$$
The spin-only magnetic moment value of the complex that absorbs light with shortest wavelength is ______ B.M. (Nearest integer)

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