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NTA JEE Main 10th April 2016 Online - Chemistry

For the following questions answer them individually

The following statements concern elements in the periodic table. Which of the following is true?

If 100 mole of $$H_2O_2$$ decompose at 1 bar and 300 K, the work is done (kJ) by one mole of $$O_2(g)$$ as it expands against 1 bar pressure is:
$$2H_2O_2(l) \rightleftharpoons 2H_2O(l) + O_2(g)$$
$$(R = 8.3$$ J K$$^{-1}$$ mol$$^{-1})$$

Identify the reaction which does not liberate hydrogen

Assertion: Among the carbon allotropes, diamond is an insulator, whereas, graphite is a good conductor of electricity.
Reason: Hybridization of carbon in diamond and graphite are sp$$^3$$ and sp$$^2$$ respectively.

Sodium extract is heated with concentrated $$HNO_3$$ before testing for halogens because:

Oxidation of succinate ion produces ethylene and carbon dioxide gases. On passing 0.2 Faraday electricity through an aqueous solution of potassium succinate, what is the total volume of gases (at both cathode and anode) at STP (1 atm and 273 K)?

Identify the correct statement:

The rate law for the reaction below is given by the expression k[A][B]
$$A + B \to$$ Product
If the concentration of B is increased from 0.1 to 0.3 mol, keeping the value of A at 0.1 mol, the rate constant will be:

Identify the incorrect statement:

The correct statement about the synthesis of erythritol $$(C(CH_2OH)_4)$$ used in the preparation of PETN is