Objective: To find out which end of an unmarked battery is positive ($$+$$) and which is negative ($$-$$).
Scientific fact used: A light-emitting diode (LED) conducts electric current in only one direction. The LED glows when its anode (the longer lead) is connected to the higher potential and its cathode (the shorter lead, often next to a flat edge on the plastic body) is connected to the lower potential.
If $$V_\mathrm{anode}$$ and $$V_\mathrm{cathode}$$ denote the potentials at the two leads, the LED behaves as follows:
\[ I = 0 \quad \text{when} \quad V_\mathrm{anode} - V_\mathrm{cathode} \lt V_f \]
\[ I \gt 0 \;\; (\text{LED glows}) \quad \text{when} \quad V_\mathrm{anode} - V_\mathrm{cathode} \ge V_f \]
Here $$V_f$$ is the forward-bias voltage of the LED. For a common red LED, $$V_f \approx 1.8\text{–}2.0\,\mathrm{V}$$ (green, blue and white LEDs need even more), so a 3 V battery (or two 1.5 V cells in series) is needed to light it.
Apparatus required
- One LED (a red LED, which needs about $$2\,\mathrm{V}$$ to glow).
- One $$220\,\Omega$$–$$470\,\Omega$$ resistor used as a current limiter.
- Two short pieces of insulated copper wire with bare ends.
- The unmarked battery whose terminals are to be identified (use a 3 V battery, or two 1.5 V cells in series, so the LED's forward voltage is comfortably exceeded).
Step-by-step procedure
- Identify the longer lead of the LED; this is its anode. The shorter lead is the cathode.
- Twist (or solder) the resistor in series with either lead of the LED. The resistor keeps the current small enough that the LED is not damaged.
- Connect one piece of wire to the free end of the resistor and another piece of wire to the remaining lead of the LED.
- Touch the two free wire ends to the two unknown terminals of the battery. Note which terminal is touched by the wire coming from the anode (long-lead) side.
- Observation
- If the LED glows, current is flowing from anode to cathode through the LED. Therefore the terminal touched by the anode-side wire is the positive (+) terminal, and the other terminal is the negative (–) terminal.
- If the LED does not glow, swap the two wires at the battery. The LED should now light up. The terminal that is now in contact with the anode-side wire is the positive (+) terminal, and the other one is the negative (–) terminal.
Result: The terminal that allows the LED to glow when joined to its longer lead (anode) is the positive terminal of the battery; the other terminal is the negative one.
Note: Any one-way (polarity-sensitive) device—a silicon diode in series with a bulb, an analogue galvanometer, or a digital multimeter set on the d.c. voltage range—could be used instead of the LED, but the LED is the quickest and safest option for a school laboratory.