Let a right circular cone have base radius $$r$$, slant height $$l$$, height $$h$$, and semi-vertical angle $$\theta$$, where
$$\sin\theta = \dfrac{r}{l}, \qquad \cos\theta = \dfrac{h}{l}, \qquad \tan\theta = \dfrac{r}{h}.$$
The total surface area (curved + base) is given to be constant:
$$S = \pi r l + \pi r^2.$$
The volume is
$$V = \dfrac{1}{3}\pi r^2 h.$$
Step 1 — Express the variables via $$\theta$$.
From $$\sin\theta = r/l$$, $$l = r/\sin\theta$$. Substituting into the surface-area equation,
$$S = \pi r \cdot \dfrac{r}{\sin\theta} + \pi r^2 = \pi r^2\!\left(\dfrac{1}{\sin\theta} + 1\right) = \dfrac{\pi r^2 (1 + \sin\theta)}{\sin\theta}.$$
Solving for $$r^2$$:
$$r^2 = \dfrac{S\sin\theta}{\pi (1 + \sin\theta)}. \qquad (1)$$
Also, $$h = l\cos\theta = \dfrac{r\cos\theta}{\sin\theta} = r\cot\theta$$. Hence
$$V = \dfrac{1}{3}\pi r^2 \cdot r\cot\theta = \dfrac{1}{3}\pi r^3 \cot\theta.$$
So
$$V^2 = \dfrac{\pi^2}{9}\, r^6 \cot^2\theta = \dfrac{\pi^2}{9} \cdot (r^2)^3 \cdot \dfrac{\cos^2\theta}{\sin^2\theta}.$$
Using (1),
$$V^2 = \dfrac{\pi^2}{9} \cdot \dfrac{S^3 \sin^3\theta}{\pi^3 (1 + \sin\theta)^3} \cdot \dfrac{\cos^2\theta}{\sin^2\theta} = \dfrac{S^3}{9\pi} \cdot \dfrac{\sin\theta\,\cos^2\theta}{(1 + \sin\theta)^3} = \dfrac{S^3}{9\pi} \cdot \dfrac{\sin\theta (1 - \sin^2\theta)}{(1 + \sin\theta)^3}.$$
Since $$1 - \sin^2\theta = (1 - \sin\theta)(1 + \sin\theta)$$,
$$V^2 = \dfrac{S^3}{9\pi} \cdot \dfrac{\sin\theta (1 - \sin\theta)}{(1 + \sin\theta)^2}.$$
Let $$s = \sin\theta$$, $$0 < s < 1$$. Maximising $$V$$ is equivalent to maximising
$$F(s) = \dfrac{s(1 - s)}{(1 + s)^2}.$$
Step 2 — Critical point.
$$F(s) = \dfrac{s - s^2}{(1 + s)^2}.$$
Differentiate using the quotient rule:
$$F'(s) = \dfrac{(1 - 2s)(1 + s)^2 - (s - s^2)\cdot 2(1 + s)}{(1 + s)^4} = \dfrac{(1 - 2s)(1 + s) - 2(s - s^2)}{(1 + s)^3}.$$
Expand the numerator:
$$(1 - 2s)(1 + s) = 1 - s - 2s^2, \qquad 2(s - s^2) = 2s - 2s^2.$$
So the numerator is
$$1 - s - 2s^2 - 2s + 2s^2 = 1 - 3s.$$
Hence
$$F'(s) = \dfrac{1 - 3s}{(1 + s)^3}.$$
Setting $$F'(s) = 0$$ gives $$s = \dfrac{1}{3}$$.
Step 3 — Confirm a maximum.
For $$0 < s < \dfrac{1}{3}$$, $$1 - 3s > 0$$ and $$(1 + s)^3 > 0$$, so $$F'(s) > 0$$ — $$F$$ is increasing.
For $$\dfrac{1}{3} < s < 1$$, $$1 - 3s < 0$$, so $$F'(s) < 0$$ — $$F$$ is decreasing.
The sign of $$F'$$ changes from positive to negative at $$s = \dfrac{1}{3}$$, so $$F$$ (and hence $$V$$) attains its maximum there.
Conclusion. $$\sin\theta = \dfrac{1}{3}$$, i.e. $$\theta = \sin^{-1}\!\left(\dfrac{1}{3}\right)$$. Proved.