Let the magnitudes of the three given vectors be equal to a common value, say $$m$$; that is
$$|\vec a| = |\vec b| = |\vec c| = m.$$
Because the vectors are mutually perpendicular, their pair-wise scalar products vanish:
$$\vec a\cdot\vec b = \vec b\cdot\vec c = \vec c\cdot\vec a = 0.$$
Form the vector
$$\vec r = \vec a + \vec b + \vec c.$$
Our task is to compare the angles that $$\vec r$$ makes with $$\vec a,\;\vec b$$ and $$\vec c$$. For a generic vector $$\vec p$$ the cosine of the angle $$\theta_p$$ between $$\vec r$$ and $$\vec p$$ is given by
$$\cos\theta_p = \dfrac{\vec r\cdot\vec p}{|\vec r|\,|\vec p|}.$$
1. Scalar products with the three given vectors
(i) With $$\vec a$$:
$$\vec r\cdot\vec a = (\vec a + \vec b + \vec c)\cdot\vec a = \vec a\cdot\vec a + \vec b\cdot\vec a + \vec c\cdot\vec a = m^{2} + 0 + 0 = m^{2}.$$
(ii) With $$\vec b$$:
$$\vec r\cdot\vec b = (\vec a + \vec b + \vec c)\cdot\vec b = \vec a\cdot\vec b + \vec b\cdot\vec b + \vec c\cdot\vec b = 0 + m^{2} + 0 = m^{2}.$$
(iii) With $$\vec c$$:
$$\vec r\cdot\vec c = (\vec a + \vec b + \vec c)\cdot\vec c = \vec a\cdot\vec c + \vec b\cdot\vec c + \vec c\cdot\vec c = 0 + 0 + m^{2} = m^{2}.$$
Thus each dot-product numerator is the same value $$m^{2}.$$
2. Magnitude of $$\vec r$$
$$|\vec r|^{2} = (\vec a + \vec b + \vec c)\cdot(\vec a + \vec b + \vec c)$$
$$= \vec a\cdot\vec a + \vec b\cdot\vec b + \vec c\cdot\vec c + 2(\vec a\cdot\vec b + \vec b\cdot\vec c + \vec c\cdot\vec a)$$
$$= m^{2} + m^{2} + m^{2} + 2(0 + 0 + 0) = 3m^{2}.$$
Hence $$|\vec r| = \sqrt{3}\,m.$$
3. Cosines of the three angles
(a) With $$\vec a$$:
$$\cos\theta_a = \dfrac{m^{2}}{|\vec r|\,m} = \dfrac{m^{2}}{(\sqrt{3}\,m)\,m} = \dfrac{1}{\sqrt{3}}.$$
(b) With $$\vec b$$:
$$\cos\theta_b = \dfrac{m^{2}}{|\vec r|\,m} = \dfrac{1}{\sqrt{3}}.$$
(c) With $$\vec c$$:
$$\cos\theta_c = \dfrac{m^{2}}{|\vec r|\,m} = \dfrac{1}{\sqrt{3}}.$$
4. Conclusion
The cosines of the angles that $$\vec r = \vec a + \vec b + \vec c$$ makes with $$\vec a,\;\vec b$$ and $$\vec c$$ are identical. Therefore the three angles themselves are equal. Hence, the vector $$\vec a + \vec b + \vec c$$ is equally inclined to each of the mutually perpendicular, equal-magnitude vectors $$\vec a,\;\vec b$$ and $$\vec c$$.
In fact, each angle equals $$\cos^{-1}\!\left(\dfrac{1}{\sqrt{3}}\right) \approx 54.7^{\circ}.$$