JEE (Advanced) 2008 Paper-2

Instructions

In hexagonal systems of crystals, a frequently encountered arrangement of atoms is described as a hexagonal prism. Here, the top and bottom of the cell are regular hexagons and three atoms are sandwiched in between them. A space-filling model of this structure, called hexagonal close-packed (HCP), is constituted of a sphere on a flat surface surrounded in the same plane by six identical spheres as closely as possible. Three spheres are then placed overthefirst layer so that they touch each other and represent the second layer. Each one of these three spheres touches three spheres of the bottom layer. Finally, the second layer is covered with a third layer that is identical to the bottom layer in relative position. Assume radius of every sphereto be ‘r’.

Question 61

The number of atoms in this HCP unitcell is

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Question 62

The volume of this HCP unitcell is

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Question 63

The emptyspace in this HCP unit cell is

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Instructions

For the following questions answer them individually

Question 64

Match the compounds in Column I with their characteristic test(s)/reaction(s) given in Column II. Indicate your answer by darkening the appropriate bubbles of the $$4 \times 4$$ matrix given in the ORS.

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Question 65

Match the conversions in Column I with the type(s) of reaction(s) given in Column II. Indicate your answer by darkening the appropriate bubbles of the $$4 \times 4$$ matrix given in the ORS

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Question 66

Match the entries in Column  I with the correctly related quantum number(s) in Column II. Indicate your answer by darkening the appropriate bubbles of the $$4 \times 4$$ matrix given in the ORS

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