Sign in
Please select an account to continue using cracku.in
↓ →
Join Our JEE Preparation Group
Prep with like-minded aspirants; Get access to free daily tests and study material.
Consider compounds A, B and C with following structural formulae
A = $$CH_3 - CH_2 - CH_2 - CH_2 - CH_2 - OH$$
B = $$CH_2 = CH - CH_2 - CH_2 - CH_3$$
C = $$HO - CH_2 - CH_2 - CH(OH) - CH_3$$
For the conversion of B from A, reagent (D) required is _______ and structural formula of product (E) obtained when C undergoes same reaction using excess reagent (D) is _______.
Compound A, $$\mathrm{CH_3CH_2CH_2CH_2CH_2OH}$$, is a primary alcohol. Conversion of A to B, $$\mathrm{CH_2=CHCH_2CH_2CH_3}$$, involves dehydration of the alcohol.
The reagents commonly used for dehydration are concentrated $$\mathrm{H_2SO_4}$$ or $$\mathrm{H_3PO_4}$$ in the presence of heat.
Hence, reagent D is concentrated $$\mathrm{H_2SO_4}$$ or $$\mathrm{H_3PO_4}$$.
Compound C is
$$\mathrm{HOCH_2CH_2CH(OH)CH_3}$$
In the presence of excess dehydrating agent, both hydroxyl groups undergo dehydration.
The first dehydration gives
$$\mathrm{CH_2=CHCH(OH)CH_3}$$
Further dehydration gives
$$\mathrm{CH_2=CHCH=CH_2}$$
The product formed is 1,3-butadiene, a conjugated diene.
Therefore,
$$\mathrm{E=CH_2=CHCH=CH_2}$$
Hence, the correct option is (D).
Create a FREE account and get:
Educational materials for JEE preparation