Sign in
Please select an account to continue using cracku.in
↓ →
Join Our JEE Preparation Group
Prep with like-minded aspirants; Get access to free daily tests and study material.
Structures of four disaccharides are given below. Among the given disaccharides, the non-reducing sugar is :
A disaccharide will behave as a reducing sugar only when **at least one** of its two monosaccharide units retains a free (hemi-acetal/ hemi-ketal) $$-OH$$ group at the anomeric carbon. Such a free anomeric $$-OH$$ can open up to the aldehydic or ketonic form and reduce mild oxidising agents like Tollens’ or Fehling’s reagents.
If **both** anomeric carbons become part of the glycosidic bond, the molecule now contains two acetal (or ketal) linkages and no free hemi-acetal/ hemi-ketal group. Then the sugar cannot get oxidised and is termed a non-reducing sugar.
Among the common disaccharides:
Inspecting the given structures, only the structure in Option B shows a $$1 \rightarrow 2$$ linkage between the anomeric carbon of an $$\alpha$$-D-glucopyranosyl unit and the anomeric carbon of a $$\beta$$-D-fructofuranosyl unit—exactly the structural feature of sucrose. Since both anomeric centres participate in the bond, there is no free hemi-acetal/ hemi-ketal group.
Therefore, the sole non-reducing disaccharide in the list is sucrose.
Option B which is: sucrose
Create a FREE account and get:
Educational materials for JEE preparation