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Which of the following graphs is correct for a second-order reaction?
The half-life equation for an $$n^{\text{th}}$$-order chemical reaction follows the general proportionality:
$$t_{1/2}\propto\frac{1}{a_0^{n-1}}$$
For a second-order reaction, n=2:
$$t_{1/2}=\frac{1}{k a_0}$$
Rearranging in the form y=mx+c:
$$t_{1/2}=\left(\frac{1}{k}\right)\left(\frac{1}{a_0}\right)+0$$
- y-axis: $$t_{1/2}$$
- x-axis: $$\frac{1}{a_0}$$
- Slope: $$\frac{1}{k}$$
- y-intercept: 0
Therefore, the graph of $$t_{1/2}$$ versus $$\frac{1}{a_0}$$ is a straight line passing through the origin with a positive slope.
Correct option: (A)
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