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Which of the following f-block elements in the +3 oxidation state is colourless?
1. $$\mathrm{La^{3+}}$$
- Configuration: $$[\mathrm{Xe}]\,4f^0$$
- Reason: It has an empty $$f$$-subshell. Without electrons, no $$f\text{-}f$$ transitions can occur to absorb visible light.
2. $$\mathrm{Gd^{3+}}$$
- Configuration: $$[\mathrm{Xe}]\,4f^7$$
- Reason: It has a half-filled $$f$$-subshell. Its electronic transitions absorb mainly in the ultraviolet region, leaving it colourless in the visible spectrum.
3. $$\mathrm{Lu^{3+}}$$
- Configuration: $$[\mathrm{Xe}]\,4f^{14}$$
- Reason: It has a completely filled $$f$$-subshell. There are no vacant orbitals available for $$f\text{-}f$$ electronic transitions.
Correct option: (D)
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