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Question 54

Three bulbs are filled with CH$$_4$$, CO$$_2$$ and Ne as shown in the picture. The bulbs are connected through pipes of zero volume. When the stopcocks are opened and the temperature is kept constant throughout, the pressure of the system is found to be ______ atm. (Nearest integer).

image


Correct Answer: 3



1. Summary of Given Experimental Data:
Gas Component Initial Pressure (P) Initial Volume (V)
Bulb 1 (CH4) 2 atm 2 L
Bulb 2 (CO2) 4 atm 3 L
Bulb 3 (Ne) 3 atm 4 L

Because temperature ($$T$$) and the total amount of gas moles ($$n$$) remain fixed and constant inside the closed setup, we can confidently apply Boyle's Law and Dalton's Law of Partial Pressures.

The fundamental law states that the sum of the initial pressure-volume pairs equals the total final system pressure-volume state.

2. Calculate Total Combined Volume ($$V_{\text{total}}$$)

Since the connecting glass pipes add zero dead volume, the final total volume is the absolute sum of all individual gas chambers:

$$V_{\text{total}} = V_1 + V_2 + V_3$$
3. Apply the System Pressure Formula

The consolidated equation used to find the final pressure of non-reacting mixed gases is:

$$P_{\text{total}} \times V_{\text{total}} = (P_1 \times V_1) + (P_2 \times V_2) + (P_3 \times V_3)$$
4. Numerical Calculations

Substitute our exact values directly into the core formula:

$$P_{\text{total}} \times 9 = (2 \times 2) + (4 \times 3) + (3 \times 4)$$
$$P_{\text{total}} \times 9 = 4 + 12 + 12$$
$$P_{\text{total}} \times 9 = 28$$
$$P_{\text{total}} = \frac{28}{9} \approx 3.11\text{ atm}$$

5. Rounding to Nearest Integer

The precise value yields 3.11 atm. Rounding off to the closest whole integer gives us 3.

Correct Answer (Nearest Integer Value): 3

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