- (i) $$\text{Na}_2\text{CO}_3\cdot10\text{H}_2\text{O}$$ (Washing Soda): Manufactured on a large scale using the Solvay process.
$$\implies \text{(i)} \rightarrow \text{(C)}$$
- (ii) $$\text{Mg(HCO}_3)_2$$ (Magnesium Bicarbonate): Soluble hydrogencarbonates of calcium and magnesium are directly responsible for causing temporary hardness in water.
$$\implies \text{(ii)} \rightarrow \text{(D)}$$
- (iii) $$\text{NaOH}$$ (Sodium Hydroxide): Industrially prepared by the electrolysis of brine solution in the Castner-Kellner process.
$$\implies \text{(iii)} \rightarrow \text{(B)}$$
- (iv) $$\text{Ca}_3\text{Al}_2\text{O}_6$$ (Tricalcium Aluminate): An essential component found in Portland cement ingredients that helps regulate its setting time.
$$\implies \text{(iv)} \rightarrow \text{(A)}$$
Conclusion:
Aligning the correct pairs leads directly to the proper combined option sequence.
Answer: (i) → (C); (ii) → (D); (iii) → (B); (iv) → (A)