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Question Stem (Q15 & Q16): Two volatile liquids A and B form an ideal solution. Consider a 5 molal solution of B in A inside a closed container having a total vapour pressure of 100 mm Hg at 300 K. The vapour pressure of pure A at 300 K is 105 mm Hg. Assume that A and B behave as ideal gases in the vapour phase.
Given: The gas constant $$R=0.08$$ L atm K$$^{-1}$$ mol$$^{-1}$$;
Molar mass of A is 50 g mol$$^{-1}$$;
Molar mass of B is 57 g mol$$^{-1}$$;
Density of liquid B at 300 K is 0.5 g/mL; 1 atm $$=760$$ mm Hg.
At 300 K, the ratio of the molar volume of pure B in vapour phase to its molar volume in liquid phase is ___.
Correct Answer: 2000.00
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