Question 21

The average translational kinetic energy of $$N_2$$ gas molecules at _________ °C becomes equal to the K.E. of an electron accelerated from rest through a potential difference of 0.1 volt.
(Given $$k_B = 1.38 \times 10^{-23}$$ J K$$^{-1}$$) (Fill the nearest integer).


Correct Answer: 500

For any ideal gas, the average translational kinetic energy per molecule is given first:

$$\text{Average K.E. per molecule} = \dfrac{3}{2}\,k_B\,T,$$

where $$k_B$$ is the Boltzmann constant and $$T$$ is the absolute temperature in kelvin.

An electron that starts from rest and is accelerated through a potential difference $$V$$ acquires kinetic energy according to the work-energy principle. The work done on a charge $$q$$ in moving through a potential difference $$V$$ is

$$\text{K.E. gained} = q\,V.$$

For an electron, the magnitude of the charge is $$e = 1.6 \times 10^{-19}\ \text{C}$$. Given that the accelerating potential difference is $$V = 0.1\ \text{V}$$, we have

$$\text{K.E. of the electron} = eV = (1.6 \times 10^{-19}\ \text{C})(0.1\ \text{V}) = 1.6 \times 10^{-20}\ \text{J}.$$

According to the statement of the question, this electron kinetic energy must equal the average translational kinetic energy of one $$\mathrm{N_2}$$ molecule. Hence we equate the two expressions:

$$\dfrac{3}{2}\,k_B\,T = 1.6 \times 10^{-20}\ \text{J}.$$

Now we substitute the given value $$k_B = 1.38 \times 10^{-23}\ \text{J K}^{-1}$$ and solve algebraically for $$T$$:

$$T = \dfrac{2}{3}\,\dfrac{1.6 \times 10^{-20}}{1.38 \times 10^{-23}}\ \text{K}.$$

Simplifying step by step, we first divide the numerical factors:

$$\dfrac{1.6}{1.38} \approx 1.1594,$$

and we handle the powers of ten separately:

$$10^{-20}\, /\,10^{-23} = 10^{3}.$$

So the fraction becomes

$$\dfrac{1.6 \times 10^{-20}}{1.38 \times 10^{-23}} \approx 1.1594 \times 10^{3} = 1.1594 \times 10^{3}.$$

Multiplying by the factor $$\dfrac{2}{3}$$ gives

$$T = \dfrac{2}{3} \times 1.1594 \times 10^{3}\ \text{K}.$$

Carrying out the multiplication,

$$\dfrac{2}{3} \times 1.1594 \approx 0.7730,$$

and finally,

$$T \approx 0.7730 \times 10^{3}\ \text{K} = 773\ \text{K}.$$

To express this temperature in degrees Celsius, we use the relation

$$T\;({}^{\circ}\text{C}) = T\;(\text{K}) - 273,$$

so

$$T\;({}^{\circ}\text{C}) = 773 - 273 = 500^{\circ}\text{C}.$$

The question asks for the nearest integer value, which is already an integer. Hence, the correct answer is Option 500.

Was this solution helpful?

Get AI Help

Video Solution

video
Ask AI