Join WhatsApp Icon JEE WhatsApp Group
Question 17

The energy levels of a hydrogen atom are shown below. The transition corresponding to emission of shortest wavelength is

image

The energy of a photon emitted during a transition is given by Planck's relation: $$\Delta E = \frac{hc}{\lambda} \implies \lambda \propto \frac{1}{\Delta E}$$

To find the shortest wavelength ($$\lambda_{\text{min}}$$), we look for the transition with the largest energy difference ($$\Delta E_{\text{max}}$$).

Energy levels of a hydrogen atom ($$E_n = -\frac{13.6}{n^2}\ \text{eV}$$):

$$E_1 = -13.6\ \text{eV}$$,  $$E_2 = -3.4\ \text{eV}$$,  $$E_3 = -1.51\ \text{eV}$$,  $$E_4 = -0.85\ \text{eV}$$

Transition A ($$n=4 \rightarrow n=3$$): $$\Delta E = -0.85 - (-1.51) = 0.66\ \text{eV}$$

Transition B ($$n=4 \rightarrow n=2$$): $$\Delta E = -0.85 - (-3.4) = 2.55\ \text{eV}$$

Transition C ($$n=3 \rightarrow n=2$$): $$\Delta E = -1.51 - (-3.4) = 1.89\ \text{eV}$$

Transition D ($$n=3 \rightarrow n=1$$): $$\Delta E = -1.51 - (-13.6) = 12.09\ \text{eV}$$

    Since transition D involves the ground state ($$n=1$$), it has the largest energy gap, which results in the shortest emitted wavelength.

    Get AI Help

    Create a FREE account and get:

    • Free JEE Mains Previous Papers PDF
    • Take JEE Mains paper tests

    JEE Quant Questions | JEE Quantitative Ability

    JEE DILR Questions | LRDI Questions For JEE

    JEE Verbal Ability Questions | VARC Questions For JEE

    Free JEE Topicwise Questions

    JEE Rotational MotionJEE Units & MeasurementsJEE Atomic StructureJEE GravitationJEE Periodic Table & PeriodicityJEE StatisticsJEE Inverse Trigonometric FunctionsJEE Magnetism & Magnetic MaterialsJEE Sequences & SeriesJEE MatricesJEE Alternating CurrentsJEE Carboxylic AcidsJEE Permutations & CombinationsJEE Work, Energy & PowerJEE Electromagnetic InductionJEE Electronic DevicesJEE d and f-Block ElementsJEE Chemical KineticsJEE Heat TransferJEE Three Dimensional GeometryJEE Magnetic Effects of CurrentJEE Hydrocarbons - AromaticJEE Electromagnetic WavesJEE Aldehydes & KetonesJEE Hydrocarbons - AlkanesJEE Applications of DerivativesJEE EquilibriumJEE Indefinite IntegrationJEE Chemical ThermodynamicsJEE ElectrochemistryJEE ProbabilityJEE BiomoleculesJEE Continuity & DifferentiabilityJEE Kinetic Theory of GasesJEE Vector AlgebraJEE Hydrocarbons - AlkynesJEE Differential EquationsJEE Current & ResistanceJEE Straight LinesJEE WavesJEE Redox ReactionsJEE Hydrocarbons - AlkenesJEE DeterminantsJEE SolutionsJEE Ray OpticsJEE Dual Nature of Matter & RadiationJEE Chemical Bonding & Molecular StructureJEE Complex NumbersJEE Sets, Relations & FunctionsJEE Electric Charges & FieldsJEE Laws of MotionJEE Fluid MechanicsJEE Basic Concepts in ChemistryJEE Trigonometric FunctionsJEE LimitsJEE Laws of ThermodynamicsJEE Kinematics - 2D MotionJEE p-Block Elements (Groups 13-18)JEE Simple Harmonic MotionJEE Electric Potential & CapacitanceJEE Coordination CompoundsJEE JEE 2D GeometryJEE CirclesJEE Definite IntegrationJEE EMF & Circuit AnalysisJEE Surface TensionJEE Atoms & NucleiJEE Laboratory Experiments - XIJEE Number SystemJEE Basic Principles of Organic ChemistryJEE Wave OpticsJEE Quadratic EquationsJEE Alcohols, Phenols & EthersJEE Organic Compounds with HalogensJEE DifferentiationJEE Conic SectionsJEE Nitrogen-Containing CompoundsJEE ElasticityJEE Practical Organic ChemistryJEE Kinematics - 1D MotionJEE Purification & CharacterisationJEE Binomial Theorem
    Ask AI