JEE (Advanced) 2010 Paper-1

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For the following questions answer them individually

JEE (Advanced) 2010 Paper-1 - Question 11


In the Newman projection for 2-2 dimethylbutane

X and Y can respectively be

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JEE (Advanced) 2010 Paper-1 - Question 12


Among the following, the intensive property is (properties are)

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JEE (Advanced) 2010 Paper-1 - Question 13


Aqueous solutions of $$HNO_{3}, KOH, CH_{3}COOH$$ and $$CH_{3}COONa$$ of identical concentrations are provided. The pair(s) of solutions which form a buffer upon mixing is(are)

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Instructions

Copper is the most noble of the first row transition metals and occurs in small deposits in several countries. Ores of copperinclude chalcanthite $$(CuSo_{4}.5H_{2}O)$$, atacamite $$(Cu_{2}Cl(OH)_{3})$$, cuprite $$Cu_{2}O$$, Copper glance $$Cu_{2}S$$ and malachite $$(Cu_{2}(OH)_{2}CO_{3})$$. However, 80% of the world copper production comes from the ore chalcopyrite $$(CuFeS_{2})$$. The extraction of copper from chalcopyrite involves partial roasting, removal of iron and self-reduction.

JEE (Advanced) 2010 Paper-1 - Question 14


Partial roasting of chalcopyrite produces

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JEE (Advanced) 2010 Paper-1 - Question 15


Iron is removed from chalcopyrite as

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JEE (Advanced) 2010 Paper-1 - Question 16


In self-reduction, the reducing species is

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The concentration of potassiumions inside a biological cell is at least twenty times higher than the outside. The resulting potential difference across the cell is important in several processes such as transmission of nerve impulses and maintaining the ion balance. A simple model for such a concentration cell involving a metal M is:
$$M(s)\mid M^{+}(aq; 0.05 molar)\mid \mid M^{+}(aq; 1 molar)\mid M(s)$$
For the above electrolytic cell the magnitude of the cell potential $$\mid E_{cell}\mid=70 mV$$.

JEE (Advanced) 2010 Paper-1 - Question 17


For the above cell

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JEE (Advanced) 2010 Paper-1 - Question 18


If the 0.05 molar solution of $$M^{+}$$ is replaced by a 0.0025 molar $$M^{+}$$ solution, then the magnitude of the cell potential would be

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For the following questions answer them individually

JEE (Advanced) 2010 Paper-1 - Question 19


The total number of basic groups in the following form of lysine is

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JEE (Advanced) 2010 Paper-1 - Question 20


The total numberof cyclic isomers possible for a hydrocarbon with the molecular formula $$C_{4}H_{6}$$ is

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