JEE (Advanced) 2010 Paper-1

Instructions

For the following questions answer them individually

Question 11

In the Newman projection for 2-2 dimethylbutane

X and Y can respectively be

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Question 12

Among the following, the intensive property is (properties are)

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Question 13

Aqueous solutions of $$HNO_{3}, KOH, CH_{3}COOH$$ and $$CH_{3}COONa$$ of identical concentrations are provided. The pair(s) of solutions which form a buffer upon mixing is(are)

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Instructions

Copper is the most noble of the first row transition metals and occurs in small deposits in several countries. Ores of copperinclude chalcanthite $$(CuSo_{4}.5H_{2}O)$$, atacamite $$(Cu_{2}Cl(OH)_{3})$$, cuprite $$Cu_{2}O$$, Copper glance $$Cu_{2}S$$ and malachite $$(Cu_{2}(OH)_{2}CO_{3})$$. However, 80% of the world copper production comes from the ore chalcopyrite $$(CuFeS_{2})$$. The extraction of copper from chalcopyrite involves partial roasting, removal of iron and self-reduction.

Question 14

Partial roasting of chalcopyrite produces

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Question 15

Iron is removed from chalcopyrite as

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Question 16

In self-reduction, the reducing species is

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Instructions

The concentration of potassiumions inside a biological cell is at least twenty times higher than the outside. The resulting potential difference across the cell is important in several processes such as transmission of nerve impulses and maintaining the ion balance. A simple model for such a concentration cell involving a metal M is:
$$M(s)\mid M^{+}(aq; 0.05 molar)\mid \mid M^{+}(aq; 1 molar)\mid M(s)$$
For the above electrolytic cell the magnitude of the cell potential $$\mid E_{cell}\mid=70 mV$$.

Question 17

For the above cell

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Question 18

If the 0.05 molar solution of $$M^{+}$$ is replaced by a 0.0025 molar $$M^{+}$$ solution, then the magnitude of the cell potential would be

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Instructions

For the following questions answer them individually

Question 19

The total number of basic groups in the following form of lysine is

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Question 20

The total numberof cyclic isomers possible for a hydrocarbon with the molecular formula $$C_{4}H_{6}$$ is

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