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Question 99

The equilibrium constant for the reaction $$N_2(g) + O_2(g) \rightleftharpoons 2NO(g)$$ at temperature $$T$$ is $$4 \times 10^{-4}$$. The value of $$K_c$$ for the reaction $$NO(g) \rightleftharpoons \frac{1}{2}N_2(g) + \frac{1}{2}O_2(g)$$ at the same temperature is

Solution

The initial reaction is:

$$N_2(g) + O_2(g) \rightleftharpoons 2NO(g) \quad \text{with } K_1 = 4 \times 10^{-4}$$

The target reaction is:

$$NO(g) \rightleftharpoons \frac{1}{2}N_2(g) + \frac{1}{2}O_2(g)$$

  • Step A: Reverse the reaction

    When a reaction is reversed, its equilibrium constant becomes the reciprocal of the original constant ($$K' = \frac{1}{K_1}$$):

    $$2NO(g) \rightleftharpoons N_2(g) + O_2(g) \quad \implies \quad K' = \frac{1}{4 \times 10^{-4}} = \frac{10^4}{4} = 2500$$

  • Step B: Multiply the reaction by $$\frac{1}{2}$$

    When a reaction is multiplied by a factor $$n$$, the new equilibrium constant is raised to the power of $$n$$:

    $$NO(g) \rightleftharpoons \frac{1}{2}N_2(g) + \frac{1}{2}O_2(g) \quad \implies \quad K_c = (K')^{1/2} = \sqrt{2500}$$    
    $$K_c = 50$$

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