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Question 59

Number of compounds which give reaction with Hinsberg's reagent is ______.

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Correct Answer: 5

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Hinsberg's reagent reacts with primary ($$1^{\circ }$$) and secondary ($$2^{\circ }$$ amines). It does not react with tertiary ($$3^{\circ }$$ amines), amides, or diazonium salts under standard conditions.Analysis of the Compounds:

  1. Benzene diazonium chloride: Does not react.
  2. Benzimide (Amide): Does not react.
  3. Aniline ($$1^{\circ }$$ amine): Reacts.
  4. $$(N)$$-phenylpiperidine ($$3^{\circ }$$ amine): Does not react.
  5. Benzyl methyl amine ($$2^{\circ }$$ amine): Reacts.
  6. Ethane-1,2-diamine ($$1^{\circ }$$ amine): Reacts.
  7. Piperidine ($$2^{\circ }$$ amine): Reacts.
  8. Pyridine ($$3^{\circ }$$ amine): Does not react.
  9. Propan-1-amine ($$1^{\circ }$$ amine): Reacts.
  10. Urea (Amide): Does not react

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